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Synthesis and structure of bis(tetraphenylantimony) malonate

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Abstract

Bis(tetraphenylantimony) malonate was synthesized by the reaction of tetraphenylantimony bromide with silver malonate (the molar ratio was 2:1) in toluene. According to the X-ray diffraction data, the tridentate carboxylate ligand is a chelate. The coordination number of the Sb(1) atom involved in a contact with the carbonyl oxygen atom increases to six (Sb(1)—O(1), 2.199(7) Å; Sb(1)—O(3), 2.362(7) Å). Another antimony atom remains five-coordinate (Sb(2)—O(4), 2.304(7) Å). The antimony atoms Sb(1) and Sb(2) have distorted octahedral and trigonal-bipyramidal coordination geometry, respectively.

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Authors and Affiliations

  1. Blagoveschensk State Pedagogical University, 104 ul. Lenina, 675000, Blagoveschensk, Russian Federation

    I. V. Egorova, V. V. Zhidkov, I. N. Zubakina & N. A. Rodionova

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  1. I. V. Egorova
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  2. V. V. Zhidkov
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  3. I. N. Zubakina
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  4. N. A. Rodionova
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Correspondence to I. V. Egorova.

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Based on the materials of the XXI Mendeleev Congress on General and Applied Chemistry (September 9–13, 2019, St. Petersburg, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1279–1283, July, 2020.

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Egorova, I.V., Zhidkov, V.V., Zubakina, I.N. et al. Synthesis and structure of bis(tetraphenylantimony) malonate. Russ Chem Bull 69, 1279–1283 (2020). https://doi.org/10.1007/s11172-020-2898-0

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  • DOI: https://doi.org/10.1007/s11172-020-2898-0

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