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Oxidation of diethyl disulfide with atmospheric oxygen in the presence of 1,3-dimethylimidazolium dimethyl phosphate

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Abstract

Oxidation of diethyl disulfide with atmospheric oxygen at 363 К in the presence of 1,3-dimethylimidazolium dimethyl phosphate is described. On the basis of the 1Н, 31Р, and 13С NMR data, it is shown that oxidation of diethyl disulfide results in ethyl sulfonates. Formation of ethyl alcohol, which is a product of a side reaction of ethyl sulfonate hydrolysis, probably, catalyzed by the 1,3-dimethylimidazolium cation, was detected using HPLC and 1Н and 13С NMR.

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Authors and Affiliations

  1. D. Mendeleev University of Chemical Technology of Russia, 9 Miusskaya pl., 125047, Moscow, Russian Federation

    E. G. Krivoborodov, A. A. Zanin, E. P. Novikova & Ya. O. Mezhuev

Authors
  1. E. G. Krivoborodov
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  2. A. A. Zanin
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  3. E. P. Novikova
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  4. Ya. O. Mezhuev
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Corresponding author

Correspondence to E. G. Krivoborodov.

Additional information

This work was financially supported by D. Mendeleev University of Chemical Technology of Russia (Project No. 036-2018).

Based on the materials of the XXI Mendeleev Congress on General and Applied Chemistry (September 9–13, 2019, St. Petersburg).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 0986–0989, May, 2020.

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Krivoborodov, E.G., Zanin, A.A., Novikova, E.P. et al. Oxidation of diethyl disulfide with atmospheric oxygen in the presence of 1,3-dimethylimidazolium dimethyl phosphate. Russ Chem Bull 69, 986–989 (2020). https://doi.org/10.1007/s11172-020-2859-7

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  • DOI: https://doi.org/10.1007/s11172-020-2859-7

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