Abstract
New trimethylhydrometallatranes, tris(2-hydroxypropyl)amine complexes with NiII, ZnII, CuII, and CoII salts of biologically active carboxylic acids (benzoic, cinnamic, salicylic, succinic), were synthesized. The structure of the tris(2-hydroxypropyl)amine complex with nickel(II) cinnamate was determined by single-crystal X-ray diff raction. Thermal stability of the synthesized tris(2-hydroxypropyl)amine complexes was compared with that of tris(2-hydroxyethyl)- amine complexes.
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The study was performed using equipment of the resource centers of the Saint Petersburg State University “Centre for Optical and Laser Materials Research,” “Centre for X-ray Diff raction Studies,” “Chemical Analysis and Materials Research Centre,” and “Magnetic Resonance Research Centre.”
Based on the materials of the XXI Mendeleev Congress on General and Applied Chemistry (September 9—13, 2019, St. Petersburg).
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 0958–0964, May, 2020.
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Kadnikova, O.Y., Kondratenko, Y.A., Gurzhiy, V.V. et al. Synthesis and structures of tris(2-hydroxypropyl)amine complexes with NiII, ZnII, CuII, and CoII salts of biologically active carboxylic acids. Russ Chem Bull 69, 958–964 (2020). https://doi.org/10.1007/s11172-020-2855-y
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DOI: https://doi.org/10.1007/s11172-020-2855-y