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Sol-gel synthesis of lithium niobate doped by zinc and boron and study of the luminescent properties of ceramics LiNbO3: Zn: B

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Abstract

A technological scheme was developed for the sol-gel synthesis of lithium niobate doped by zinc and boron with sol-gel method, and the optimal conditions at each stage of the process were determined. The limiting concentrations of doping impurities, at which a single-phase charge can be synthesized, were established. A ceramic composition LiNbO3: Zn: B with a bulk weight of ~2.3 g cm−3 is formed during the thermal treatment of the hydrate residue at 1100 ?? and an exposure for 3 h. Owing to the proposed method the product quality can be increased and the cost of the syntgesis of the LiNbO3: Zn: B ceramics minimized. The study of the luminescence properties of the ceramics based on the charge prepared from the charge mixture synthesized by the sol-gel method revealed that boron in the lithium niobate structure is an activator of luminescence in the high-energy visible spectral range. The obtained results can serve as a basis for the technology of production of both crystalline and ceramic new functional materials.

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Authors and Affiliations

  1. I. V. Tananaev Institute of Rare Element and Mineral Chemistry and Technology, Kola Research Center, Russian Academy of Sciences, 26a Akademgorodok, 184209, Apatity, Russian Federation

    S. M. Masloboeva, M. V. Smirnov & M. N. Palatnikov

Authors
  1. S. M. Masloboeva
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  2. M. V. Smirnov
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  3. M. N. Palatnikov
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Correspondence to S. M. Masloboeva.

Additional information

Based on the materials of the XXI Mendeleev Congress on General and Applied Chemistry (September 9-13, 2019, St. Petersburg, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 0947–0951, May, 2020.

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Masloboeva, S.M., Smirnov, M.V. & Palatnikov, M.N. Sol-gel synthesis of lithium niobate doped by zinc and boron and study of the luminescent properties of ceramics LiNbO3: Zn: B. Russ Chem Bull 69, 947–951 (2020). https://doi.org/10.1007/s11172-020-2853-0

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  • DOI: https://doi.org/10.1007/s11172-020-2853-0

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