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New one-, two-, and three-dimensional metal-organic frameworks based on magnesium(II): synthesis and structure

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Abstract

Six new metal-organic frameworks based on magnesium(II) ions of various dimensionality were synthesized: chain-like [Mg(Hazdc)2(nmp)2] (1, H2azdc is 4,4′-azobenzenedicarboxylic acid, nmp is N-methylpyrrolidone), layered [Mg(H2btc)(nmp)2] (2, H4btc is 1,2,4,5-benzene-tetracarboxylic acid), [Mg3(sdc)3(def)4] •3DEF (3, H2sdc is 4,4’-stilbenedicarboxylic acid, def or DEF is N,N-diethylformamide), [Mg3(azdc)3(dma)4] • 3DMA (4, dma or DMA is N,N-di-methylacetamide), [Mg3(azdc)3(dmf)4] (5, dmf is N,N-dimethylformamide), and doubly-interpenetrated three-dimensional [Mg3(azdc)3(nmp)4] •NMP (6, NMP is N-methylpyrrolidone). According to the single-crystal X-ray dif raction data, compounds 1 and 2 are built from mononuclear carboxylate units {Mg(RCOOH)2(RCOO)2(nmp)2}. Compounds 3-6 are composed on trinuclear carboxylate units {Mg3(RCOO)6}. In isostructural compounds 3-5, these units are linked to each other through carboxylate bridges to form polymer layers; in compound 6, these units are linked together to form a doubly-interpenetrated three-dimensional metal-organic framework.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrentieva, 630090, Novosibirsk, Russian Federation

    A. V. Marakulin, A. A. Lysova, D. G. Samsonenko, D. N. Dybtsev & V. P. Fedin

  2. Novosibirsk State University, 2 ul. Pirogova, 630090, Novosibirsk, Russian Federation

    A. V. Marakulin, A. A. Lysova, D. G. Samsonenko, D. N. Dybtsev & V. P. Fedin

  3. National Research Center “Kurchatov Institute”, 1 ul. Akad. Kurchatova, 123182, Moscow, Russian Federation

    P. V. Dorovatovskii & V. A. Lazarenko

Authors
  1. A. V. Marakulin
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  2. A. A. Lysova
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  3. D. G. Samsonenko
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  4. P. V. Dorovatovskii
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  5. V. A. Lazarenko
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  6. D. N. Dybtsev
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  7. V. P. Fedin
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Corresponding author

Correspondence to V. P. Fedin.

Additional information

Based on the materials of the International Markovnikov Congress on Organic Chemistry (June 21–28, 2019, Moscow-Kazan, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 0360—0368, February, 2020.

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Marakulin, A.V., Lysova, A.A., Samsonenko, D.G. et al. New one-, two-, and three-dimensional metal-organic frameworks based on magnesium(II): synthesis and structure. Russ Chem Bull 69, 360–368 (2020). https://doi.org/10.1007/s11172-020-2768-9

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  • DOI: https://doi.org/10.1007/s11172-020-2768-9

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