Skip to main content
SpringerLink
Log in

Ethylene polymerization using immobilized fluorine-containing bis-salicylidenimine-titanium complexes

  • Full Articles
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

A fluorine-containing bis-salicylidenimine-titanium(iv) complex TiCl2{η2-1-[C(H)=NC6F4]-2-O-Ph(But)2}2 has been synthesized and immobilized on silica gel, polysorb, and magnesium chloride. The catalytic properties of heterogenized complexes activated by organoaluminum compounds (OAC) have been studied in ethylene polymerization. it has been demonstrated that the activity of the catalytic systems obtained by simultaneous immobilization of the complex, OAC, and [Me2NHPh]+[B(C6F5)4]− is an order of magnitude higher than in the absence of perfluorophenylborate. Catalysts on inorganic supports exhibit higher activity than catalysts on polymer supports. The use of anhydrous magnesium chloride as a support makes it possible to obtain a highly efficient catalyst for the synthesis of ultrahigh molecular weight polyethylene (activity up to 1350 (kg of polymer) (mol Ti h atm)−1, melting point 140–143 °C).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Reference

  1. M. Mitani, J. Saito, S. Ishii, Y. Nakayama, H. Makio, N. Matsukawa, S. Matsui, J. Mohri, R. Furuyama, H. Terao, H. Bando, H. Tanaka, T. Fujita, Chem. Rec., 2004, 4, 137.

    Article  CAS  Google Scholar 

  2. H. Makio, T. Fujita, Acc. Chem. Res., 2009, 42, 532.

    Article  Google Scholar 

  3. T. Matsugia, T. Fujita, Chem. Soc. Rev., 2008, 37, 1264.

    Article  Google Scholar 

  4. H. Makio, H. Terao, A. Iwashita, T. Fujita, Chem. Rev., 2011, 111, 2363.

    Article  CAS  Google Scholar 

  5. G. G. Hlatky, Chem. Rev., 2000, 100, 1347.

    Article  CAS  Google Scholar 

  6. J. R. Severn, J. C. Chadwick, R. Duchateau, N. Friederichs, Chem. Rev., 2005, 105, 4073.

    Article  CAS  Google Scholar 

  7. J. R. Severn, J. C. Chadwick, Dalton Trans., 2013, 42, 8979.

    Article  CAS  Google Scholar 

  8. W. Li, H. Yang, J. Zhang, J. Mu, D. Gong, X. Wang, Chem. Commun., 2016, 52, 11092.

    Article  CAS  Google Scholar 

  9. F. Yu, Y. Yang, D. He, D. Gong, Z.-R. Chen, Ind. Eng. Chem. Res., 2017, 56, 4684.

    Article  CAS  Google Scholar 

  10. C. Naundorf, S. Matsui, J. Saito, T. Fujita, M. Klapper, K. Müllen, J. Polym. Sci., Part A: Polym. Chem., 2006, 44, 3103.

    Article  CAS  Google Scholar 

  11. A. Sattler, D. C. Aluthge, J. R. Winkler, J. A. Labinger, J. E. Bercaw, ACS Catalysis, 2016, 6, 19.

    Article  CAS  Google Scholar 

  12. T. Repo, M. Kinga, P. Pietikäainen, M. Leskeläa, A.-M. Uusitalo, T. Pakkanen, K. Hakala, P. Aaltonen, B. Löofgren, Macromolecules, 1997, 30, 171.

    Article  CAS  Google Scholar 

  13. H. H. Brintzinger, D. Fischer, R. Műlhaupt, B. Rieger, R. M. Waymouth, Ang. Chem., Int. Ed. Engl., 1995, 34, 1143.

    Article  CAS  Google Scholar 

  14. M. Bochmann, J. Chem. Soc., Dalton Trans., 1996, 255.

  15. M. C. Baier, M. A. Zuideveld, S. Mecking, Ang. Chem., Int. Ed. Engl., 2014, 53, 9722.

    Article  CAS  Google Scholar 

  16. H. Bekker, H. Domchke, E. Fanghenel, Organikum, Organisch Chemisches Grundpraktikum, VEB Deutscher Verlag der Wissenschaften, Berlin, 1990.

    Google Scholar 

  17. S. Ch. Gagieva, T. A. Sukhova, D. V. Savinov, D. A. Optov, N. M. Bravaya, Yu. N. Belokoń, B. M. Bulychev, Russ. Chem. Bull., 2003, 52, 1693.

    Article  CAS  Google Scholar 

  18. M. Seeger, W. Otto, W. Flick, F. Bickelhaupt, O. S. Akkerman, Magnesium Compounds, Ullmann’s Encyclopedia of Industrial Chemistry, Weinheim, Wiley-VCH, 2012, 12, 41.

    Google Scholar 

  19. S. Howell, E. J. Shields, Powder Surface Area and Porosity, Chapman and Hall, London, 1984.

    Google Scholar 

  20. O. M. Chukanova, S. L. Saratovskikh, O. N. Babkina, N. M. Bravaya, Vysokolmol. soed., Ser. A, 2001, 43, 1285 [Polymer. Sci., Ser. A (Engl. Transl.), 2001, 43] (in Russian).

    CAS  Google Scholar 

  21. O. M. Chukanova, S. L. Saratovskikh, O. N. Babkina, L. A. Rishina, P. M. Nedorezova, N. M. Bravaya, Vysokolmol. soed., Ser. A, 2003, 45, 1268 [Polymer. Sci., Ser. A (Engl. Transl.), 2003, 45] (in Russian).

    CAS  Google Scholar 

  22. O. M. Chukanova, A. N. Panin, N. M. Bravaya, Vysokolmol. soed., Ser. A, 2005, 47, 1491 [Polymer. Sci., Ser. A (Engl. Transl.), 2005, 47] (in Russian).

    CAS  Google Scholar 

  23. O. M. Chukanova, A. N. Panin, N. M. Bravaya, Polymer Sci., 2005, 47, 855.

    Google Scholar 

  24. M. Mitani, J. Saito, S. Ishii, Y. Nakayama, H. Makio, N. Matsukawa, S. Matsui, J. Mohri, R. Furuyama, H. Terao, H. Bando, H. Tanaka, T. Fujita, Chem. Rec., 2004, 4, 137.

    Article  CAS  Google Scholar 

  25. F. Schaper, A. Geyer, H.-H. Brintzinger, Organometallics, 2002, 21, 473.

    Article  CAS  Google Scholar 

  26. G. G. Hlatky, D. J. Upton, Macromolecules, 1996, 29, 8019.

    Article  CAS  Google Scholar 

  27. S. Rastogi, D.R. Lippits, G. W. M. Peters, R. Graf, Y. Yao, H. W. Spiess, Nat. Mater., 2005, 4, 635.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, M. V. Lomonosov Moscow State University, 1 Leninskie Gory, 119991, Moscow, Russian Federation

    S. Ch. Gagieva, V. A. Tuskaev, O. V. Smirnova & B. M. Bulychev

  2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    S. Ch. Gagieva, V. A. Tuskaev, R. U. Takazova & A. G. Buyanovskaya

  3. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Acad. Semenova, Chernogolovka, Moscow Region, 142432, Russian Federation

    N. M. Bravaya

Authors
  1. S. Ch. Gagieva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. A. Tuskaev
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. R. U. Takazova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. G. Buyanovskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. O. V. Smirnova
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. N. M. Bravaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. B. M. Bulychev
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to S. Ch. Gagieva.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2114–2118, November, 2019.

The work was financially supported by the Russian Science Foundation (Project No. 16-13-10502) and the Russian Foundation for Basic Research (Project No. 17-03-00234, fabrication of pre-catalyst of TiIV).

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Gagieva, S.C., Tuskaev, V.A., Takazova, R.U. et al. Ethylene polymerization using immobilized fluorine-containing bis-salicylidenimine-titanium complexes. Russ Chem Bull 68, 2114–2118 (2019). https://doi.org/10.1007/s11172-019-2675-0

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-019-2675-0

Key words

Search

Navigation