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N,N-Di(pyridin-2-yl)quinolin-6-amine: synthesis and coordination properties

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Abstract

N,N-Di(pyridin-2-yl)quinolin-6-amine which is a new ditopic fluorescent ligand based on di(pyridin-2-yl)amine was synthesized and characterized. Using the methods of fluorescence and UV-vis spectroscopy, the complex formation of this ligand with the CoII, NiII, QuII, ZnII and PbII cations in acetonitrile was studied, the composition and the stability constants of the resulting complexes were determined. Their structure was studied by NMR using the zinc complex as an example.

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Authors and Affiliations

  1. Department of Chemistry, M. V. Lomonosov Moscow State University, 1-3 Leninskie Gory, 119991, Moscow, Russian Federation

    A. D. Kharlamova, A. S. Abel, A. D. Averin & I. P. Beletskaya

  2. A. N. Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences, 31-4, Leninsky prosp., 119991, Moscow, Russian Federation

    A. D. Averin & I. P. Beletskaya

Authors
  1. A. D. Kharlamova
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  2. A. S. Abel
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  3. A. D. Averin
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  4. I. P. Beletskaya
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Correspondence to A. S. Abel.

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Kharlamova, A.D., Abel, A.S., Averin, A.D. et al. N,N-Di(pyridin-2-yl)quinolin-6-amine: synthesis and coordination properties. Russ Chem Bull 68, 597–600 (2019). https://doi.org/10.1007/s11172-019-2460-0

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  • DOI: https://doi.org/10.1007/s11172-019-2460-0

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