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Synthesis of fluorescent coumarin-labeled organic glass

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Abstract

Polymerization of methyl methacrylate in bulk in the presence of 4-ethynylcoumarin and 4-butadiynylcoumarin (AIBN, 60 °C) leads to the formation of fluorescent polymers. A hypsochromic shift of fluorescence band maxima of polymer solutions is observed in dichloromethane. It was suggested using the quantum chemical calculations that 4-ethynylcoumarin is attached to the macroradical via the terminal carbon atom of the ethynyl group. The samples of fluorescent organic glasses were prepared. It was established that the addition of coumarins do not influence the microhardness of organic glass.

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Authors and Affiliations

  1. N. I. Lobachevsky Nizhny Novgorod State University, 23 prosp. Gagarina, 603950, Nizhny Novgorod, Russian Federation

    Yu. L. Kuznetsova, A. V. Nyuchev, S. K. Ignatov, A. S. Vavilova & A. Yu. Fedorov

  2. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603137, Nizhny Novgorod, Russian Federation

    N. A. Lenshina, M. A. Lopatin, S. A. Chesnokov & M. P. Shurygina

Authors
  1. Yu. L. Kuznetsova
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  2. A. V. Nyuchev
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  3. N. A. Lenshina
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  4. M. A. Lopatin
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  5. S. K. Ignatov
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  6. S. A. Chesnokov
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  7. M. P. Shurygina
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  8. A. S. Vavilova
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  9. A. Yu. Fedorov
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Corresponding author

Correspondence to Yu. L. Kuznetsova.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1671–1678, September, 2018.

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Kuznetsova, Y.L., Nyuchev, A.V., Lenshina, N.A. et al. Synthesis of fluorescent coumarin-labeled organic glass. Russ Chem Bull 67, 1671–1678 (2018). https://doi.org/10.1007/s11172-018-2275-4

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  • DOI: https://doi.org/10.1007/s11172-018-2275-4

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