Skip to main content
Log in

Hydroxyl-containing imidazolium ionic liquids

  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

A number of imidazolium ionic liquids with bis(trifluoromethylsulfonyl)imide anion containing a ω-hydroxyalkyl substituent of different lengths in the cation (nС = 2–8) were synthesized. The properties of the obtained liquids were investigated by DSC, TGA, IR, and NMR spectroscopy. Their thermal stability was studied; melting points, viscosity, and volatility in vacuum were measured. The possibility of using synthesized ionic liquids as heat carriers under high vacuum conditions is demonstrated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Q. Yang, Z. Zhang, X.-G. Sun, Y.-S. Hu, H. Xing, S. Dai, Chem. Soc. Rev., 2018, 47, 2020.

    Article  CAS  PubMed  Google Scholar 

  2. J. Le Bideau, L. Viau, A. Vioux, Chem. Soc. Rev., 2011, 40,907.

    Article  PubMed  Google Scholar 

  3. V. A. Azov, K. S. Egorova, M. M. Seitkalieva, A. S. Kashin, V. P. Ananikov, Chem. Soc. Rev., 2018, 47, 1250.

    Article  CAS  PubMed  Google Scholar 

  4. А. Roessler, H. Schottenberger, Prog. Org. Coat., 2014, 77, 579.

    Article  CAS  Google Scholar 

  5. А. Tsurumaki, S. Tajima, T. Iwata, B. Scrosati, H. Ohno, Electrochim. Acta, 2017, 248,556.

    Article  CAS  Google Scholar 

  6. V. P. Ananikov, K. I. Galkin, M. P. Egorov, A. M. Sakharov, S. G. Zlotin, E. A. Redina, V. I. Isaeva, L. M. Kustov, M. L. Gening, N. E. Nifantiev, Mendeleev Commun., 2016, 26,365.

    Article  CAS  Google Scholar 

  7. C. D. Hubbard, P. Illne, R. van Eldik, Chem. Soc. Rev., 2011, 40,272.

    Article  CAS  PubMed  Google Scholar 

  8. I. V. Kuchurov, M. N. Zharkov, L. L. Fershtat, N. N. Makhova, S. G. Zlotin, ChemSusChem, 2017, 10, 3914.

    Article  CAS  PubMed  Google Scholar 

  9. S. Wegner, C. Janiak, Top. Curr. Chem. (Z), 2017, 375,65.

    Article  CAS  Google Scholar 

  10. Catalysis in Ionic Liquids: From Catalyst Synthesis to Application, Eds C. Hardacre, V. Parvulescu, The Royal Society of Chemistry, 2014; http://pubs.rsc.org/en/content/ebook/978-1-84973-603-9.

  11. F. Zhou, Y. Liang, W. Liu, Chem. Soc. Rev., 2009, 38, 2590.

    Article  CAS  PubMed  Google Scholar 

  12. X. Wang, Y. Chi, T. Mu, J. Mol. Liq., 2014, 193,262.

    Article  CAS  Google Scholar 

  13. J. Liu, F. Wang, L. Zhang, X. Fang, Z. Zhang, Renew. Energy, 2014, 63,519.

    Article  CAS  Google Scholar 

  14. T. C. Paul, A. K. M. M. Morshed, E. B. Fox, J. A. Khan, App. Therm. Eng., 2017, 110,1.

    Article  CAS  Google Scholar 

  15. E. A. Chernikova, L. M. Glukhov, V. G. Krasovskiy, L. M. Kustov, M. G. Vorob′eva, A. A. Koroteev, Russ. Chem. Rev., 2015, 84,875.

    Article  CAS  Google Scholar 

  16. V. G. Krasovskiy, L. M. Glukhov, E. A. Chernikova, G. I. Kapustin, O. B. Gorbatsevich, A. A. Koroteev, L. M. Kustov, Russ. Chem. Bull., 2017, 66, 1269.

    Article  CAS  Google Scholar 

  17. V. G. Krasovskiy, E. A. Chernikova, L. M. Glukhov, E. A. Redina, G. I. Kapustin, A. A. Koroteev, L. M. Kustov, Mendeleev Commun., 2017, 27,605.

    Article  CAS  Google Scholar 

  18. H. L. Ngo, K. LeCompte, L. Hargens, A. B. McEwen, Thermochim. Acta, 2000, 357–358,97.

    Article  Google Scholar 

  19. M. J. Earle, J. M. S. S. Esperança, M. A. Gilea, J. N. Canongia Lopes, L. P. N. Rebelo, J. W. Magee, K. R. Seddon, J. A. Widegren, Nature, 2006, 439,831.

    Article  CAS  PubMed  Google Scholar 

  20. G. Yu, D. Zhao, L. Wen, S. Yang, X. Chen, AIChE J., 2012, 58, 2885.

    Article  CAS  Google Scholar 

  21. S. Zhang, X. Qi, X. Ma, L. Lu, Y. Deng, J. Phys. Chem. B, 2010, 114, 3912.

    Article  CAS  PubMed  Google Scholar 

  22. P. A. Hunt, C. R. Ashworth, R. P. Matthews, Chem. Soc. Rev., 2015, 44, 1257.

    Article  CAS  PubMed  Google Scholar 

  23. M. S. Sandhya, V. Govinda, I. Bahadur, P. Venkateswarlu, J. Mol. Liq., 2017, 240,613.

    Article  CAS  Google Scholar 

  24. Y. Nikawa, K. Fujita, H. Ohno, Phys. Chem. Chem. Phys., 2017, 19, 8148.

    Article  CAS  PubMed  Google Scholar 

  25. M. Kosmulski, J. Gustafsson, J. B. Rosenholm, Thermochim. Acta, 2004, 412,47.

    Article  CAS  Google Scholar 

  26. C. Maton, N. De Vos, C. V. Stevens, Chem. Soc. Rev., 2013, 42, 5963.

    Article  CAS  PubMed  Google Scholar 

  27. B. Liu, Y. Liu, Env. Eng. Sci., 2016, 33,384.

    Article  CAS  Google Scholar 

  28. Z. Xue, Y. Zhang, X. Zhou, Y. Cao, T. Mu, Thermochim. Acta, 2014, 578,59.

    Article  CAS  Google Scholar 

  29. Solution Chemistry Research Progress, Ed. D. V. Bostrelli, New York, Nova Science, 2011, 187 pp.

  30. I. H. J. Arellano, J. G. Guarino, F. U. Paredes, S. D. Arco, J. Therm. Anal. Calorim., 2011, 103,725.

    Article  CAS  Google Scholar 

  31. L. М. Glukhov, V. G. Krasovskiy, G. I. Kаpustin, L. М. Kustov, А. А. Kоroteev Russ. J. Phys. Chem. A, 2015, 89, 2204.

    Article  CAS  Google Scholar 

  32. Е. А. Chernikova, L. М. Glukhov, V. G. Krasovskiy, L. М. Kustov, А. А. Kоroteev, in Mater. nauchnoi konferentsii grantopoluchatelei RNF "Fundamentalnye khimicheskie issledovaniya XXI veka" [Proc. Scientific Conference for Grant Receiver of RSF "Fundamental Chemical Investigation in XXI century"] (20–24 November, 2016), Moscow, 2016, p. 601 (in Russian).

    Google Scholar 

  33. L. I. Zakharkin, V. I. Stanko, V. A. Brattsev, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1961, 10, 1938.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to V. G. Krasovskiy.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1621–1626, September, 2018.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Krasovskiy, V.G., Chernikova, Е.А., Glukhov, L.М. et al. Hydroxyl-containing imidazolium ionic liquids. Russ Chem Bull 67, 1621–1626 (2018). https://doi.org/10.1007/s11172-018-2268-3

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-018-2268-3

Key words

Navigation