Abstract
A method for the quantification of small amounts (0.01–0.03 mol L–1) of ionic liquids (IL) [BMIM]Br, Bu4NBr, and Bu4NHSO4 in solutions using CHN analysis was proposed. The sample preparation procedure is based on evaporating the volatile components from the solution and concentrating of IL in an inert porous material (SiO2). Prior to preparation and analysis, the solid samples were heated at a temperature selected based on DTA data. This procedure can be used to determine the content of IL in solutions and catalytic mixtures.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Ionic Liquids in Synthesis, Eds P. Wasserscheid, T. Velton, Wiley-VCH, 2002,262.
V. G. Krasovskiy, E. A. Chernikova, L. M. Glukhov, E. A. Redina, G. I. Kapustin, A. A. Koroteev, L. M. Kustov, Mendeleev Commun., 2017, 27,605.
S. V. Savilov, A. O. Artemova, A. S. Ivanov, Z. Shen, S. M. Aldoshin, V. V. Lunin, Mendeleev Commun., 2016, 26,240.
V. A. Azov, K. S. Egorova, M. M. Seitkalieva, A. S. Kashin, V. P. Ananikov, Chem. Soc. Rev., 2018, 47, 1250.
J. P. Hallett, T. Welton, Chem. Rev., 2011, 111, 3508.
G. Loubna, D. Manfred, A. Ulrich, Curr. Org. Synth., 2009, 6,342.
A. Zazubin, Kh. Rafikova, V. Yu, D. Zolotareva, V. M. Dembitsky, T. Sasaki, Russ. Chem. Rev., 2017, 86, 1254.
H. Shirkhanloo, M. Ghazaghi, A. Rashidi, A. Vahid, Microhem. J., 2017, 130,137.
M. Amide, J.-F. Liu, Z. Q. Tan, D. Bekana, Talanta, 2016, 149,341.
V. Abbasi, A. Sarafraz-Yazdi, A. Amiri, H. Vatani, J. Chromatogr. Sci., 2016, 54,677.
A. Gure, F. J. Lara, A. M. Garcia-Campaña, N. Megersa, M. Del Olmo-Iruelaq, Food Chem., 2015, 170,348.
M. V. Shashkov, V. N. Sidelnikov, J. Chromatogr. A., 2013, 1309,56.
L. A. Kartsova, E. A. Bessonova, E. A. Kolobova, Russ. J. Analyt. Chem., 71,141.
B. Aghabarari, N. Dorostkar, M. N. Martinez-Huerta, Fuel Proc. Techn., 2014, 118,296.
A. Marcinek, J. Zielonka, J. Gebicki, C. M. Gordon, I. R. Dunkin, J. Phys. Chem. A, 2001, 105, 9305.
K. Kamata, M. Katani, K. Yamaguchi, H. Hikichi, N. Mizuno, Chem.–A Eur. J., 2007, 13,639.
C. Yuan, X. Gao, Z. Pan, X. Li, Z. Tan, Catal. Commun., 2015, 58,215.
L. I. Kuznetsova, N. I. Kuznetsova, R. I. Maksimovskaya, G. I. Aleshina, O. S. Koscheeva, V. A. Utkin, Catal. Lett., 2011, 141, 1442.
S. Xue, G. Chen, Z. Long, Y. Zhou, J. Wang, RSC Adv., 2015, 5, 19306.
L. I. Kuznetsova, N. I. Kuznetsova, V. N. Zudin, V. F. Utkin, D. V. Trebushat, M. A. Fedotov, T. V. Larina, Catal. Lett., 2014, 144, 1499.
E. M. Siedlecka, W. Mrozik, Z. Kaczynski, P. Stepnowski, J. Hazard. Mater., 2008, 154,893.
Ch. J. Rao, R. V. Krishnan, K. A. Venkatesan, K. Nagarajan, T. G. Srinivasan, J. Therm. Anal. Calorim., 2009, 97,937.
C. A. Hawkins, A. Rud, M. L. Guthrie, M. L. Dietz, J. Chromatogr. A, 2015, 1400,54.
C. Lu, Z. Tang, C. Liu, X. Chen, Y. Wang, F. Dang, Analyt. Meth., 2015, 7, 5924.
M. J. Marluszewski, P. Stepnovski, M. P. Marszall, Electrophoresis, 2004, 25, 3450.
A. Markovska, P. Stepnovswki, J. Sep. Sci., 2010, 33, 1991.
L. I. Kuznetsova, N. I. Kuznetsova, O. S. Koscheeva, Catal. Commun., 2017, 88,50.
A. Y. El-Naggar, J. Emerg. Trends Eng. Appl. Sci., 2013, 4,144.
V. M. Bondareva, T. V. Andrushkevich, R. I. Maksimovskaya, L. M. Plyasova, A. V. Ziborov, G. S. Litvak, L. G. Detusheva, Kinet. Catal., 1994, 35, 114.
Author information
Authors and Affiliations
Corresponding author
Additional information
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1617–1620, September, 2018.
Rights and permissions
About this article
Cite this article
Koscheeva, O.S., Kuznetsova, N.I. & Kuznetsova, L.I. Quantification of small amounts of ionic liquids in solutions using CHN analysis. Russ Chem Bull 67, 1617–1620 (2018). https://doi.org/10.1007/s11172-018-2267-4
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11172-018-2267-4