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Synthesis, structure, and luminescent properties of lanthanide complexes containing 1,10-phenanthroline and perfluorinated 2-mercaptobenzothiazolate ligands

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Abstract

Mononuclear terbium and erbium complexes of the composition Ln(mbtF)3phen and the dinuclear complex Tb2(mbtF)4(OH)2(phen)2 (mbtF is 4,5,6,7-tetrafluoro-2-mercaptobenzothiazolate, phen is 1,10-phenanthroline) were synthesized. The structures of the complexes Er(mbtF)3phen and Tb2(mbtF)4(OH)2(phen)2 were determined by X-ray diffraction. In the solid state, the terbium and erbium complexes exhibit intense metal-centered photoluminescence. Based on the complexes Ln(mbtF)3phen, double-layer organic light-emitting diodes (OLEDs) were assembled. These OLEDs exhibit electroplex emission with a band maximum at 630 nm.

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Authors and Affiliations

  1. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603950, Nizhny Novgorod, Russian Federation

    L. I. Blinova, V. A. Ilichev, R. V. Rumyantsev, G. K. Fukin & M. N. Bochkarev

  2. N. I. Lobachevsky Nizhny Novgorod State University, 23 prosp. Gagarina, 603950, Nizhny Novgorod, Russian Federation

    L. I. Blinova & M. N. Bochkarev

Authors
  1. L. I. Blinova
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  2. V. A. Ilichev
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  3. R. V. Rumyantsev
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  4. G. K. Fukin
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  5. M. N. Bochkarev
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Corresponding author

Correspondence to L. I. Blinova.

Additional information

Based on the materials of the XXVII International Chugaev Conference on Coordination Chemistry (October 2–6, 2017; Nizhny Novgorod, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1261–1267, July, 2018.

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Blinova, L.I., Ilichev, V.A., Rumyantsev, R.V. et al. Synthesis, structure, and luminescent properties of lanthanide complexes containing 1,10-phenanthroline and perfluorinated 2-mercaptobenzothiazolate ligands. Russ Chem Bull 67, 1261–1267 (2018). https://doi.org/10.1007/s11172-018-2210-8

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  • DOI: https://doi.org/10.1007/s11172-018-2210-8

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