Skip to main content
SpringerLink
Log in

Synthesis and Luminescent Properties of Lanthanide Complexes with Benzothiazolylphenolate and -Naphtholate Ligands

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

Sm, Er, and Yb complexes containing anionic (4,5,6,7-tetrafluorobenzothiazol-2-yl)-2-(3,4,5,6-tetrafluoro)phenolate (SONF) and 3-(2-benzothiazol-2-yl)-2-naphtholate (NpSON) and neutral 1,10-phenathroline or 2,2'-bipyridine ligands were synthesized. The structures of complexes Yb(SONF)2-(NpSON)(DME)1.5 (II) and previously synthesized Er(SONF)3(DME) (I) were determined by X-ray diffraction (CIF files CCDC nos. 1972769 and 1972770, respectively). Upon excitation by light at λ 405 nm, all complexes showed luminescence of the ligands and Ln3+ ions. The OLED devices based on samarium complexes showed moderate intensi metal-centered emission of moderate intensity at a 19 V voltage.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.
Fig. 7.
Fig. 8.
Fig. 9.

Similar content being viewed by others

REFERENCES

  1. New, E.J., Parker, D., Smith, D.G., and Walton, J.W., Curr. Opin. Chem. Biol., 2010, vol. 14, p. 238.

    Article  CAS  Google Scholar 

  2. Egorova, A.V., Skripinets, Yu.V., Aleksandrova, D.I., and Antonovich, V.P., Metody i Ob’’ekty Khim.Analiza, 2010, vol. 5, p. 180.

    Google Scholar 

  3. Hovinen, J. and Guy, P.M., Biocojugate Chem., 2009, vol. 20, p. 404.

    Article  CAS  Google Scholar 

  4. Hagan, A.K. and Zuchner, T., Anal. Bioanal. Chem., 2011, vol. 400, p. 2847.

    Article  CAS  Google Scholar 

  5. Binnemans, K., Chem. Rev., 2009, vol. 109, p. 4283.

    Article  CAS  Google Scholar 

  6. Eliseeva, S.V. and Bunzli, J.-C., Chem. Soc. Rev., 2010, vol. 39, p. 189.

    Article  CAS  Google Scholar 

  7. Bochkarev, M.N., Vitukhnovskii, A.G., and Katkova, M.A., Organicheskie svetoizluchayushchie diody (OLED) (Organic Light-Emitting Diodes (OLEDs)), Nizhny Novgorod: DEKOM, 2011.

  8. Blasse, G. and Grabmaier, B.C., Luminescent Materials, Berlin (Germany): Springer, 1994.

    Book  Google Scholar 

  9. Sun, R.G., Wang, Y.Z., Zheng, Q.B., et al., J. Appl. Phys., 2000, vol. 87, p. 7589.

    Article  CAS  Google Scholar 

  10. Kuriki, K., Koike, Y., and Okamoto, Y., Chem. Rev., 2002, vol. 102, p. 2347.

    Article  CAS  Google Scholar 

  11. Hasegawa, Y., Ohkubo, T., Sogabe, K., et al., Angew. Chem., Int. Ed. Engl., 2000, vol. 39, p. 357.

    Article  CAS  Google Scholar 

  12. Zhang, J., Badger, P.D., Geib, S.J., and Petoud, S., Angew. Chem., Int. Ed. Engl., 2005, vol. 44, p. 2508.

    Article  CAS  Google Scholar 

  13. Zheng, Y.X., Lin, J., Liang, Y.J., et al., J. Mater. Chem., 2001, vol. 11, p. 2615.

    Article  CAS  Google Scholar 

  14. Hasegawa, Y., Kimura, Y., Murakoshi, K., et al., J. Phys. Chem., 1996, vol. 100, p. 10201.

    Article  CAS  Google Scholar 

  15. Tsaryuk, V., Turowska-Tyrk, I., Legendziewicz, J., et al., J. Alloys Compd., 2002, vol. 341, p. 323.

    Article  CAS  Google Scholar 

  16. Bünzli, J.-C.G. and Piguet, C., Chem. Soc. Rev., 2005, vol. 34, p. 1048.

    Article  Google Scholar 

  17. Zhong, G., Kim, K., and Jin, J.-I., Synth. Met., 2002, vol. 129, p. 193.

    Article  CAS  Google Scholar 

  18. Armaroli, N., De Cola, L., Balzani, V., et al., J. Chem. Soc., Faraday Trans., 1992, p. 553.

  19. Bradley, D.C., Ghotra, J.S., and Hart, F.A., Dalton Trans., 1973, vol. 10, p. 1021.

    Article  Google Scholar 

  20. Burin, M.E., Kuzyaev, D.M., Lopatin, M.A., et al., Synth. Met., 2013, vol. 164, p. 55.

    Article  CAS  Google Scholar 

  21. Li, Z., Dellali, A., Malik, J., et al., Inorg. Chem., 2013, vol. 52, p. 1379.

    Article  CAS  Google Scholar 

  22. Balashova, T.V., Burin, M.E., Ilichev, V.A., et al., Molecules, 2019, vol. 24, p. 2376.

    Article  CAS  Google Scholar 

  23. Balashova, T.V., Baranov, E.V., Fukin, G.K., et al., Russ. J. Coord. Chem., 2019, vol. 45, p. 712. https://doi.org/10.1134/S107032841909001X

    Article  CAS  Google Scholar 

  24. SAINT. Version 8.38A. Data Reduction and Correction Program, Madison: Bruker AXS Inc., 2012.

  25. Krause, L., Herbst-Irmer, R., Sheldrick, G.M., and Stalke, D., J. Appl. Crystallogr., 2015, vol. 48, p. 3.

    Article  CAS  Google Scholar 

  26. Sheldrick, G.M., Acta Crystallogr., Sect. A: Found. Adv., 2015, vol. 71, p. 3.

    Article  Google Scholar 

  27. Sheldrick, G.M., Acta Crystallogr., Sect. C: Struct. Chem., 2015, vol. 71, p. 3.

    Article  Google Scholar 

  28. Shannon, R.D., Acta Crystallogr., Sect. A: Cryst. Phys., Diffr., Theor. Gen. Crystallogr., 1976, vol. 32, p. 751.

    Article  Google Scholar 

  29. Batsanov, S.S., Inorg. Mater., 2001, vol. 37, p. 871.

    Article  CAS  Google Scholar 

  30. Aspinall, H.C., Bacsa, J., Beckingham, O.D., et al., Dalton Trans., 2014, vol. 43, p. 1434.

    Article  CAS  Google Scholar 

  31. Balashova, T.V., Pushkarev, A.P., Rumyantcev, R.V., et al., J. Organomet. Chem., 2015, vol. 777, p. 42.

    Article  CAS  Google Scholar 

  32. Balashova, T.V., Ilichev, V.A., Grishin, I.D., et al., Inorg. Chim. Acta, 2018, vol. 483, p. 379.

    Article  CAS  Google Scholar 

  33. Janiak, C., Dalton Trans., 2000, no. 21, p. 3885.

  34. Pushkarev, A.P., Ilichev, V.A., Maleev, A.A., et al., J. Mater. Chem. C, 2014, vol. 2, no. 8, p. 1532.

    Article  CAS  Google Scholar 

  35. Balashova, T.V., Ilichev, V.A., Grishin, I.D., et al., Inorg. Chim. Acta, 2018, vol. 483, p. 379.

    Article  CAS  Google Scholar 

  36. Balashova, T.V., Pushkarev, A.P., Il’ichev, V.A., et al., Russ. Chem. Bull., 2016, vol. 65, no. 7, p. 1739.

    Article  CAS  Google Scholar 

  37. Balashova, T.V., Pushkarev, A.P., Il’ichev, V.A., et al., Polyhedron, 2013, vol. 50, p. 112.

    Article  CAS  Google Scholar 

Download references

ACKNOWLEDGMENTS

The study was carried out using the equipment of “Analytical Center of the IOMC RAS” (Zentr Kolektivnogo Polzovaniya) in G.A. Razuvaev Institute of Organometallic Chemistry RAS with the financial support of the Federal objective program “Research and development in priority directions of advancement of science and technology complex of Russia for 2014−2020” (Unique project identifier is RFMEFI62120X0040).

Funding

This study was supported by the Russian Science Foundation (project no. 18-13-00066).

Author information

Authors and Affiliations

  1. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia

    T. V. Balashova, S. K. Polyakova, A. A. Kukinov, R. V. Rumyantcev, G. K. Fukin, V. A. Ilichev & M. N. Bochkarev

  2. Lobachevsky State University of Nizhny Novgorod, Nizhny Novgorod, Russia

    S. K. Polyakova, A. A. Kukinov, I. D. Grishin & M. N. Bochkarev

Authors
  1. T. V. Balashova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. K. Polyakova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. A. Kukinov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. I. D. Grishin
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. R. V. Rumyantcev
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. G. K. Fukin
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. V. A. Ilichev
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. M. N. Bochkarev
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to T. V. Balashova.

Ethics declarations

The authors declare that they have no conflicts of interest.

Additional information

The authors congratulate Academician I.L. Eremenko on his 70th birthday

Translated by Z. Svitanko

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Balashova, T.V., Polyakova, S.K., Kukinov, A.A. et al. Synthesis and Luminescent Properties of Lanthanide Complexes with Benzothiazolylphenolate and -Naphtholate Ligands. Russ J Coord Chem 46, 534–544 (2020). https://doi.org/10.1134/S1070328420080011

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070328420080011

Keywords:

Search

Navigation