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Unique hyper-kagome atomic order in geometrically frustrated iridium spinel-like structures

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Abstract

The review briefly outlines the results of authors’ theoretical research into unique hyperkagome atomic and orbital order in geometrically frustrated iridium spinel-like structures. The structural mechanism of formation of the hyper-kagome atomic order is established. It is shown that closed loops of Ir—Ir bonds represent a fundamental feature of the iridium spinel-like structures. Each loop consists of ten atoms, thus being a decagon. We assume that decagons are responsible for abnormal chemical and physical properties of crystals. A prediction is made of structural types of crystals in which the hyper-kagome atomic order can exist.

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Authors and Affiliations

  1. Southern Federal University, Research Institute of Physics, 194 prosp. Stachki, 344090, Rostov-on-Don, Russian Federation

    M. V. Talanov

  2. Platov South-Russian State Polytechnic University, 132 ul. Prosveshcheniya, 346400, Novocherkassk, Russian Federation

    V. M. Talanov

  3. Southern Federal University, Faculty of Physics, 5 ul. Zorge, 344090, Rostov-on-Don, Russian Federation

    V. B. Shirokov

  4. Southern Scientific Center of the Russian Academy of Sciences, 41 ul. Chekhova, 344006, Rostov-on-Don, Russian Federation

    V. B. Shirokov

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  1. M. V. Talanov
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Correspondence to V. M. Talanov.

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Based on the Materials of the XX Mendeleev Congress on General and Applied Chemistry (September 26—30, 2016, Ekaterinburg, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1719—1727, October, 2017.

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Talanov, M.V., Talanov, V.M. & Shirokov, V.B. Unique hyper-kagome atomic order in geometrically frustrated iridium spinel-like structures. Russ Chem Bull 66, 1719–1727 (2017). https://doi.org/10.1007/s11172-017-1948-8

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