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Optically active derivatives of terephthalic acid: synthesis and crystal structures

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Abstract

New optically active derivatives of terephthalic acid, which are of interest as precursors of chiral metal-organic frameworks (MOFs), were synthesized starting from available dimethyl 2-aminoterephthalate, N-Boc-l-alanine, and N-Boc-l-proline. The crystal structures of three samples were determined by powder X-ray diffraction. In all three structures, the acid molecules exist as zwitterions.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    V. V. Veselovsky, A. V. Lozanova & V. I. Isaeva

  2. Department of Chemistry, M. V. Lomonosov Moscow State University, 1 Leninskie Gory, 119899, Moscow, Russian Federation

    A. A. Lobova & V. V. Chernyshev

  3. A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119071, Moscow, Russian Federation

    V. V. Chernyshev

Authors
  1. V. V. Veselovsky
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  2. A. V. Lozanova
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  3. V. I. Isaeva
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  4. A. A. Lobova
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  5. V. V. Chernyshev
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Corresponding authors

Correspondence to V. V. Veselovsky or V. V. Chernyshev.

Additional information

Dedicated to Academician of the Russian Academy of Sciences G. A. Abakumov on the occasion of his 80th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1589—1596, September, 2017.

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Veselovsky, V.V., Lozanova, A.V., Isaeva, V.I. et al. Optically active derivatives of terephthalic acid: synthesis and crystal structures. Russ Chem Bull 66, 1589–1596 (2017). https://doi.org/10.1007/s11172-017-1928-z

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  • DOI: https://doi.org/10.1007/s11172-017-1928-z

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