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Selective aqueous-phase hydrogenation of furfural to cyclopentanol over PdRu/C catalyst

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Abstract

The bimetallic PdRu catalyst supported on carbon nanotubes were found ot provide an efficient synthesis of cyclopentanol in aqueous-phase hydrogenation of furfural. Under the chosen reaction conditions (temperature of 473 K, total pressure of 8 MPa), the selectivity towards cyclopentanol reaches 77% at a complete conversion of furfural. A high activity of this catalyst can be associated with changes in the electronic state and dispersion of the supported metals caused by their mutual interaction and formation of PdRu alloy.

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Authors and Affiliations

  1. Institute of Hydrocarbons Processing, Siberian Branch of the Russian Academy of Sciences, 54 ul. Neftezavodskaya, 644040, Omsk, Russian Federation

    R. M. Mironenko, O. B. Belskaya, A. V. Lavrenov & V. A. Likholobov

  2. Dostoevsky Omsk State University, 55a prosp. Mira, 644077, Omsk, Russian Federation

    R. M. Mironenko

  3. Omsk State Technical University, 11 prosp. Mira, 644050, Omsk, Russian Federation

    O. B. Belskaya & V. A. Likholobov

  4. Omsk Scientific Center, Siberian Branch of the Russian Academy of Sciences, 15 prosp. Marksa, 644024, Omsk, Russian Federation

    V. A. Likholobov

Authors
  1. R. M. Mironenko
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  2. O. B. Belskaya
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  3. A. V. Lavrenov
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  4. V. A. Likholobov
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Correspondence to R. M. Mironenko.

Additional information

Based on the materials of the V All-Russian Scientific School-Conference "Chemistry under the Sigma Sign: Studies, Innovations, Technologies" (May 15—20, 2016, Omsk, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 0673—0676, April, 2017.

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Mironenko, R.M., Belskaya, O.B., Lavrenov, A.V. et al. Selective aqueous-phase hydrogenation of furfural to cyclopentanol over PdRu/C catalyst. Russ Chem Bull 66, 673–676 (2017). https://doi.org/10.1007/s11172-017-1790-z

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  • DOI: https://doi.org/10.1007/s11172-017-1790-z

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