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Alkylation of phenol with olefins in the presence of catalysts based on mesoporous aromatic frameworks

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Abstract

Mesoporous polyaromatic frameworks (PAFs) based on tetraphenylmethane were obtained and modified with sulfonic acid groups. The compounds were characterized by solid-state 13C NMR and IR spectroscopy, low-temperature nitrogen adsorption-desorption, and transmission electron microscopy. The acidities of the PAF-1-SO3H and PAF-2-SO3H samples determined by titration were 3.99 mmol g–1 and 0.91 mmol g–1, respectively. The catalytic activity of PAF-SO3H for alkylation of phenol with linear terminal olefins was investigated. The reaction products were isomeric monoalkylphenols (C-alkylates), and alkyl phenyl ethers (O-alkylates).

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Authors and Affiliations

  1. Department of Chemistry, M. V. Lomonosov Moscow State University, Build. 3, 1 Leninskie Gory, 119992, Moscow, Russian Federation

    E. A. Karakhanov, Ma Gotszyun, I. S. Kryazheva, M. Yu. Talanova & M. V. Terenina

Authors
  1. E. A. Karakhanov
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  2. Ma Gotszyun
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  3. I. S. Kryazheva
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  4. M. Yu. Talanova
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  5. M. V. Terenina
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Correspondence to E. A. Karakhanov.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 0039—0046, January, 2017.

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Karakhanov, E.A., Gotszyun, M., Kryazheva, I.S. et al. Alkylation of phenol with olefins in the presence of catalysts based on mesoporous aromatic frameworks. Russ Chem Bull 66, 39–46 (2017). https://doi.org/10.1007/s11172-017-1697-8

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  • DOI: https://doi.org/10.1007/s11172-017-1697-8

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