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Alkylation of Aromatic Compounds in the Presence of Catalysts Based on Mesoporous Phenol–Formaldehyde Polymers

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Abstract

A catalyst based on a mesoporous phenol–formaldehyde polymer (MPF) as an organic support modified with the IMHSO4 ionic liquid has been synthesized. The catalytic activity of the sample has been studied in the alkylation of aromatic compounds with octene-1. It has been found that the use of the catalyst in phenol alkylation leads to the formation of both alkylphenols (C-alkylates) and alkyl phenyl ethers (O-alkylates) with a total yield of up to 60%. In the case of alkylation of benzene and benzene derivatives, significant conversion values (45–50%) are achieved only for toluene and anisole.

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References

  1. A. Aitani, J. B. Wang, I. Wang, et al., Catal. Surv. Asia 18, 12 (2014).

    Google Scholar 

  2. R. Pal, T. Sarkar, and S. Khasnobis, Rev. Acc. 1, 570 (2012).

    Google Scholar 

  3. A. Sakthivel, S. K. Badamali, and P. Selvam, Microporous Mesoporous Mater. 39, 45 (2000).

    Article  Google Scholar 

  4. R. Skoda-Földes, Molecules 19, 8840 (2014).

    Article  Google Scholar 

  5. Y. Zhang, Q. Jiao, B. Zhen, et al., Appl. Catal., A 453, 327 (2013).

    Article  CAS  Google Scholar 

  6. C. Decastro, E. Sauvage, M. H. Valkenberg, and W. F. Hölderich, J. Catal. 196, 86 (2000).

    Article  CAS  Google Scholar 

  7. Z. Xu, H. Wan, J. Miao, et al., J. Mol. Catal. A: Chem. 332, 152 (2010).

    Article  CAS  Google Scholar 

  8. L. Rodríguez-Pérez, E. Teuma, A. Falqui, et al., Chem. Commun., 4201 (2008)).

    Google Scholar 

  9. M. Vafaeezadeh, Z. B. Dizicheh, and M. M. Hashemi, Catal. Commun. 41, 96 (2013).

    Article  CAS  Google Scholar 

  10. J. Sun, J. Yang, S. Li, and X. Xu, Catal. Commun. 83, 35 (2016).

    Article  CAS  Google Scholar 

  11. C. De Castro, E. Sauvage, M. H. Valkenberg, and W. F. Holderich, J. Catal. 196, 86 (2000).

    Article  Google Scholar 

  12. L. Lou, Y. Dong, K. Yu, et al., J. Mol. Catal. A: Chem. 333, 20 (2010).

    Article  CAS  Google Scholar 

  13. H. Zhao, N. Yu, Y. Ding, et al., Microporous Mesoporous Mater. 136, 10 (2010).

    Article  CAS  Google Scholar 

  14. A. Wilke, J. Yuan, M. Antonietti, and J. Weber, ACS Macro. Lett. 1, 1028 (2012).

    Article  CAS  Google Scholar 

  15. Z. Yang, Y. Zhao, G. Ji, et al., Green Chem. 16, 3724 (2014).

    Article  CAS  Google Scholar 

  16. E. Karakhanov, M. Boronoev, V. Ignatyeva, et al., J. Inorg. Organomet. Polym. Mater. 26, 1253 (2016).

    Article  CAS  Google Scholar 

  17. E. A. Karakhanov, M. P. Boronoev, V. I. Ignat’eva, et al., Pet. Chem. 57, 673 (2017).

    Article  CAS  Google Scholar 

  18. C. Yao, H. Li, H. Wu, et al., Catal. Commun. 10, 1099 (2009).

    Article  CAS  Google Scholar 

  19. Y. Meng, D. Gu, F. Q. Zhang, et al., Chem. Mater. 18, 4447 (2006).

    Article  CAS  Google Scholar 

  20. D. Zhao, J. Feng, Q. Huo, et al., Science 279, 548 (1998).

    Article  CAS  Google Scholar 

  21. W. Zhang, Q. Wang, H. Wu, et al., Green Chem. 16, 4767 (2014).

    Article  CAS  Google Scholar 

  22. E. B. Burgina, V. G. Ponomareva, V. P. Baltakhinov, and V. G. Kostrovskii, Zh. Strukt. Khim. 46, 630 (2005).

    Google Scholar 

  23. M. Freirea, D. Mendes, L. Freitas, et al., Catal. Today 289, 192 (2017).

    Article  Google Scholar 

Download references

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Correspondence to E. A. Karakhanov.

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Original Russian Text © M.P. Boronoev, Ma Gotszyun, M.Yu. Talanova, E.A. Karakhanov, 2018, published in Neftekhimiya, 2018, Vol. 58, No. 3.

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Boronoev, M.P., Gotszyun, M., Talanova, M.Y. et al. Alkylation of Aromatic Compounds in the Presence of Catalysts Based on Mesoporous Phenol–Formaldehyde Polymers. Pet. Chem. 58, 412–417 (2018). https://doi.org/10.1134/S0965544118050043

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  • DOI: https://doi.org/10.1134/S0965544118050043

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