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Nickel catalysis for hydrogenation of p-dinitrobenzene to p-phenylenediamine

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Abstract

The activity of supported nickel catalysts (5–20% Ni) in the hydrogenation of p-dinitrobenzene to p-phenylenediamine was investigated. The catalysts were obtained by ureainduced precipitation. Activated carbon, alumina, titania, and silica gel were evaluated as supports. The most active catalysts, 5%Ni/TiO2 and 20%Ni/SiO2, provided 50–54% yields of p-phenylenediamine at complete dinitrobenzene conversion.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    E. V. Shuvalova, O. A. Kirichenko & L. M. Kustov

  2. Department of Chemistry, M. V. Lomonosov Moscow State University, Build. 3, 1 Leninskie Gory, 119992, Moscow, Russian Federation

    L. M. Kustov

Authors
  1. E. V. Shuvalova
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  2. O. A. Kirichenko
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  3. L. M. Kustov
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Correspondence to E. V. Shuvalova.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 0034—0038, January, 2017.

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Shuvalova, E.V., Kirichenko, O.A. & Kustov, L.M. Nickel catalysis for hydrogenation of p-dinitrobenzene to p-phenylenediamine. Russ Chem Bull 66, 34–38 (2017). https://doi.org/10.1007/s11172-017-1696-9

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  • DOI: https://doi.org/10.1007/s11172-017-1696-9

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