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Polyelectrolyte capsules for controlled binding/release of fluorescent probe

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Abstract

Nanocapsules containing pyrene, a fluorescent probe, are formed on micelles of a cationic surfactant by layer-by-layer deposition of oppositely charged polyelectrolytes (polyacrylic acid/ polyethyleneimine). Approaches, which allow to evaluate the release time of pyrene from the capsules are developed. The synthesized capsules make it possible to slow down the deactivation process of the excited pyrene molecule by almost an order of magnitude by adding a quenching compound to the bulk medium and through that, prolong its operation as fluorescent probe.

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Correspondence to A. B. Mirgorodskaya.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 0675—0679, March, 2016.

Dedicated to Academician of the Russian Academy of Sciences N. S. Zefirov on the occasion of his 80th birthday.

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Ibragimova, A.R., Mirgorodskaya, A.B., Zakharova, L.Y. et al. Polyelectrolyte capsules for controlled binding/release of fluorescent probe. Russ Chem Bull 65, 675–679 (2016). https://doi.org/10.1007/s11172-016-1354-7

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  • DOI: https://doi.org/10.1007/s11172-016-1354-7

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