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Polyelectrolyte micro- and nanocapsules with varied shell permeability controlling the rate of esters hydrolysis

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Abstract

Two variants of layer-by-layer deposition of polyelectrolytes (polyacrylic acid and polyethyleneimine) for the encapsulation of low-molecular-weight hydrophobic substrates (carboxylic acid esters) were proposed. The spectrophotometric method was used to study the kinetics of alkaline hydrolysis of the esters by monitoring the permeability of microcapsule shells. The first procedure provides a preliminary microencapsulation of substrates into the carbonate matrix to form stable capsules 7–10 μm in size with a low wall permeability. According to the second procedure, the polyelectrolytes were adsorbed directly on the dispersed substrate. In this case, nanosized capsules are formed, whose permeability is controlled by the ultrasonic treatment and the number of deposited layers.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation

    E. A. Vasilieva, A. R. Ibragimova, A. B. Mirgorodskaya, E. I. Yackevich, A. B. Dobrynin, I. R. Nizameev, M. K. Kadirov, L. Ya. Zakharova & A. I. Konovalov

  2. Kazan National Research Technological University, 68 ul. K. Marksa, 420015, Kazan, Russian Federation

    E. A. Vasilieva & L. Ya. Zakharova

  3. Kazan Institute of Biochemistry and Biophysics, Kazan Scientific Center of the Russian Academy of Sciences, Box 30, 420111, Kazan, Russian Federation

    Yu. F. Zuev

Authors
  1. E. A. Vasilieva
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  2. A. R. Ibragimova
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  3. A. B. Mirgorodskaya
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  4. E. I. Yackevich
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  5. A. B. Dobrynin
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  6. I. R. Nizameev
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  7. M. K. Kadirov
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  8. L. Ya. Zakharova
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  9. Yu. F. Zuev
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  10. A. I. Konovalov
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Corresponding author

Correspondence to A. B. Mirgorodskaya.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 0232–0238, January, 2014.

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Vasilieva, E.A., Ibragimova, A.R., Mirgorodskaya, A.B. et al. Polyelectrolyte micro- and nanocapsules with varied shell permeability controlling the rate of esters hydrolysis. Russ Chem Bull 63, 232–238 (2014). https://doi.org/10.1007/s11172-014-0418-9

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  • DOI: https://doi.org/10.1007/s11172-014-0418-9

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