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A novel water-soluble sulfide cluster of iron: synthesis, properties, and intercalation into molybdenum disulfide

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Abstract

A novel water-soluble sulfide cluster of iron, {Fe6S8[P(CH2OH)3]6}2+, was obtained from ferrous chloride tetrahydrate, tris(hydroxymethyl)phosphine, and H2S in methanol. A reaction of the cluster in solution with dispersed molybdenum disulfide gave an inclusion compound, MoS2({Fe6S8[P(CH2OH)3]6}Cl2)0.06. The products obtained were characterized by IR, NMR, and ESR spectroscopy, electronic absorption spectroscopy, mass spectrometry, and elemental analysis. The magnetic susceptibility of the cluster was studied in solution and in a molybdenum disulfide matrix.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrent’eva, 630090, Novosibirsk, Russian Federation

    A. V. Anyushin, E. V. Korotaev, A. Yu. Andreeva, M. R. Ryzhikov, D. A. Mainichev, M. N. Sokolov & V. P. Fedin

  2. Novosibirsk State University, 2 ul. Pirogova, 630090, Novosibirsk, Russian Federation

    A. V. Anyushin, M. N. Sokolov & V. P. Fedin

Authors
  1. A. V. Anyushin
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  2. E. V. Korotaev
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  3. A. Yu. Andreeva
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  4. M. R. Ryzhikov
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  5. D. A. Mainichev
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  6. M. N. Sokolov
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  7. V. P. Fedin
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Correspondence to A. V. Anyushin.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 0173—0180, January, 2016.

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Anyushin, A.V., Korotaev, E.V., Andreeva, A.Y. et al. A novel water-soluble sulfide cluster of iron: synthesis, properties, and intercalation into molybdenum disulfide. Russ Chem Bull 65, 173–180 (2016). https://doi.org/10.1007/s11172-016-1280-8

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  • DOI: https://doi.org/10.1007/s11172-016-1280-8

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