Skip to main content
SpringerLink
Log in

Structure and dynamics of concentrated micellar solutions of sodium dodecyl sulfate

  • Full Articles
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

In micellar solutions of sodium dodecyl sulfate, as the concentration of surfactants increases, the spheroid shape of the micelles changes from almost spherical to ellipsoidal with increasing ratio of half-axes ratio, and further the transition to cylindrical micelles occurs. The micelles in an aqueous solution can directly contact (compact aggregates) or be separated from one another by layers of intermicellar medium (periodical colloid structures). In the latter case, the thickness of the layer can significantly exceed the micelle size, and then no mutual correlation in micelle arrangement is observed. According to the data of small-angle X-ray scattering, the relationship between the surfactant concentration and formation of “quasi-crystalline” micellar structure is nonlinear, which can be due to both micelle aggregation processes and nonuniformity of their structure. The possible influence of ordered micellar structures on the diffusion mobility of micelles is shown.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. N. A. Mazer, G. B. Benedek, M. C. Carey, J. Phys. Chem., 1976, 80, 1075.

    Article  CAS  Google Scholar 

  2. F. H. Quina, P. M. Nassar, J. B. S. Bonilha, B. L. Bales, J. Phys. Chem., 1995, 99, 17028.

    Article  CAS  Google Scholar 

  3. J. S. Collura, D. E. Harrison, C. J. Richards, T. K. Kole, M. R. Fisch, J. Phys. Chem. B, 2001, 105, 4846.

    Article  CAS  Google Scholar 

  4. M. Sammalkorpi, M. Karttunen, M. Haataja, J. Phys. Chem. B, 2007, 111, 11722.

    Article  CAS  Google Scholar 

  5. A. Jusufi, A.-P. Hynninen, M. Haataja, A. Z. Panagiotopoulos, J. Phys. Chem. B, 2009, 113, 6314.

    Article  CAS  Google Scholar 

  6. F. Palazzesi, M. Calvaresi, F. Zerbetto, Soft Matter, 2011, 7, 9148.

    Article  CAS  Google Scholar 

  7. P. J. Missel, N. A. Mazer, M. C. Carey, G. B. Benedek, J. Phys. Chem., 1989, 93, 8354.

    Article  CAS  Google Scholar 

  8. L. J. Magid, J. Phys. Chem. B, 1998, 102, 4064.

    Article  CAS  Google Scholar 

  9. K. D. Danov, P. A. Kralchevsky, K. P. Ananthapadmanabhan, Adv. Coll. Interface Sci., 2014, 206, 17.

    Article  CAS  Google Scholar 

  10. P. H. Nelson, G. C. Rutledge, T. A. Hatton, J. Chem. Phys., 1997, 107, 10777.

    Article  CAS  Google Scholar 

  11. T. Lazaridis, B. Mallik, Y. Chen, J. Phys. Chem. B, 2005, 109, 15098.

    Article  CAS  Google Scholar 

  12. G. S. Hartley, Nature, 1949, 163, 767.

    Article  CAS  Google Scholar 

  13. I. F. Efremov, Periodicheskie kolloidnye struktury [Periodical Colloid Structures], Khimiya, Leningrad, 1971, 192 pp. (in Russian).

  14. I. F. Efremov, O. G. Us’yarov, Colloid J. (Engl. Transl.), 1972, 34, 213 [Kolloid. Zh., 1972, 34, 213].

    CAS  Google Scholar 

  15. P. Kekicheff, C. Grabielle-Madelmont, M. Ollivon, J. Colloid Interface Sci., 1989, 131, 112.

    Article  CAS  Google Scholar 

  16. M. G. Noro, W. M. Gelbart, J. Phys. Chem. B, 1997, 101, 8642.

    Article  CAS  Google Scholar 

  17. G. Colafemmina, D. Fiorentino, A. Ceglie, E. Carretti, E. Fratini, L. Dei, P. Baglioni, G. Palazzo, J. Phys. Chem. B, 2007, 111, 7184.

    Article  CAS  Google Scholar 

  18. P. Brocca, L. Cantu, M. Corti, E. Del Favero, A. Raudino, Langmuir, 2007, 23, 3067.

    Article  CAS  Google Scholar 

  19. J. Merta, M. Torkkeli, T. Ikonen, R. Serimaa, P. Stenius, Macromolecules, 2001, 34, 2937.

    Article  CAS  Google Scholar 

  20. J. V. Joshi, V. K. Aswal, P. S. Goyal, J. Phys.: Condens. Matter, 2007, 19, 196219.

    Google Scholar 

  21. O. Söderman, P. Stilbs, Prog. Nucl. Magn. Reson., 1994, 26, 445.

    Article  Google Scholar 

  22. O. Söderman, P. Stilbs, W. S. Price, Concepts Magn. Reson. Part A, 2004, 23, 121.

    Article  Google Scholar 

  23. E. Pettersson, D. Topgaard, P. Stilbs, O. Söderman, Langmuir, 2004, 20, 1138.

    Article  CAS  Google Scholar 

  24. Yu. F. Zuev, R. Kh. Kurbanov, B. Z. Idiyatullin, O. G. Us’yarov, Colloid J. (Engl. Transl.), 2007, 69, 444 [Kolloid. Zh., 2007, 69, 482].

    CAS  Google Scholar 

  25. Yu. F. Zuev, O. I. Gnezdilov, O. S. Zueva, O. G. Us’yarov, Colloid J. (Engl. Transl.) 2011, 73, 59 [Kolloid. Zh., 2011, 73, 43].

    CAS  Google Scholar 

  26. O. I. Gnezdilov, Yu. F. Zuev, O. S. Zueva, K. S. Potarikina, O. G. Us’yarov, Appl. Magn. Reson., 2011, 40, 91.

    Article  CAS  Google Scholar 

  27. L R. Bogdanova, N. N. Benevolenskaya, A. O. Borovskaya, E. A. Sharipova, O. S. Zueva, Yu. F. Zuev, Butlerovskie soobshcheniya [Butlerov Communications], 2013, 35, 74 (in Russian).

    Google Scholar 

  28. C. Tanford, J. Phys. Chem., 1974, 78, 2469.

  29. J. Israelachvili, D. J. Mitchell, B. W. Ninham, J. Chem. Soc., Faraday Trans., 1976,72, 1525.

    Article  Google Scholar 

  30. A. I. Rusanov, Mitselloobrazovanie v rastvorakh poverkhnostnoaktivnykh veshchestv [Micelle Formation in Solutions of Surfactants], Khimiya, St. Petersburg, 1992, 280 pp. (in Russian).

  31. X. Tang, P. H. Koenig, R. G. Larson, J. Phys. Chem. B, 2014, 118, 3864.

    Article  CAS  Google Scholar 

  32. E. A. Reshetnyak, O. S. Chernysheva, N. A. Nikitina, L. P. Loginova, N. O. Mchedlov-Petrossyan, Colloid J. (Engl. Transl.), 2014, 76, 358 [Kolloid. Zh., 2014, 76, 389].

    CAS  Google Scholar 

  33. B. Z. Idiyatullin, K. S. Potarikina, Yu. F. Zuev, O. S. Zueva, O. G. Us’yarov, Colloid J. (Engl. Transl.), 2013, 75, 532 [Kolloid. Zh., 2013, 75, 585].

    CAS  Google Scholar 

  34. L. P. Loginova, L. V. Samokhina, N. O. Mchedlov-Petrossyan, V. I. Alekseeva, L. P. Savvina, Colloids Surf. A, 2001, 193, 207.

    Article  CAS  Google Scholar 

  35. R. Nagarajan, E. Ruckenstein, Langmuir, 1991, 7, 2934.

    Article  CAS  Google Scholar 

  36. R. Nagarajan, Langmuir, 2002, 18, 31.

    Article  CAS  Google Scholar 

  37. M. Sammalkorpi, M. Karttunen, M. Haataja, J. Phys. Chem. B, 2007, 111, 11722.

    Article  CAS  Google Scholar 

  38. P. Bernadó, J. García de la Torre, M. Pons, J. Mol. Recognit., 2004, 17, 397.

    Article  Google Scholar 

  39. W. K. Lim, A. R. Denton, J. Chem. Phys., 2014, 141, 114909.

    Article  Google Scholar 

  40. E. Del Favero, P. Brocca, V. Rondelli, S. Motta, A. Raudino, L. Cantu, Langmuir, 2014, 30, 9157.

    Article  Google Scholar 

  41. SAXS Version 4.0 Software Reference Manual, M86E00005–0600. Bruker AXS Inc., Madison, 2000.

  42. SASView 3.0.0, 2009—2013, University of Tennessee; http://www.sasview.org.

  43. P. V. Konarev, V. V. Volkov, A. V. Sokolova, M. H. J. Koch, D. I. Svergun, J. Appl. Cryst., 2003, 36, 1277.

    Article  CAS  Google Scholar 

  44. D. Wu, A. Chen, C. S. Johnson, J. Magn. Reson., 1995, A 115, 260.

    Article  CAS  Google Scholar 

  45. S. Pianegonda, E. Trizac, Y. Levin, J. Chem. Phys., 2007, 126, 014702.

    Article  Google Scholar 

  46. J. M. Falcón-González, R. Castañeda-Priego, J. Chem. Phys., 2010, 133, 216101.

    Article  Google Scholar 

  47. G. Kitzhofer, O. Koch, G. Pulverer, Ch. Simon, E. B. Weinmüller, J. Numer. Anal., Indust. Appl. Math., 2010, 5, 113.

    Google Scholar 

  48. N. V. Lebedeva, A. Shahine, B. L. Bales, J. Phys. Chem. B, 2005, 109, 19806.

    Article  CAS  Google Scholar 

  49. H. Nakahara,O. Shibata, Y. Moroi, Langmuir, 2005, 21, 9020.

    Article  CAS  Google Scholar 

  50. T. Zemb, P. Charpin, J. Physique, 1985, 46, 249.

    Article  CAS  Google Scholar 

  51. S. Vass, J. S. Pedersen, J. Plestil, P. Laggner, E. Retfalvi, I. Varga, T. Gilányi, Langmuir, 2008, 24, 408.

    Article  CAS  Google Scholar 

  52. S. H. Chen, Ann. Rev. Phys. Chem., 1986, 37, 351.

    Article  CAS  Google Scholar 

  53. J. B. Hayter, J. Penfold, J. Chem. Soc., Faraday Trans., 1981, 77, 1851.

    Article  CAS  Google Scholar 

  54. Y. S. Chao, E. Y. Sheu, S. H. Chen, J. Phys. Chem., 1985, 89, 4862.

    Article  CAS  Google Scholar 

  55. B. Svens, J. B. Rosenholm, J. Colloid Interface Sci., 1973, 44, 495.

    Article  CAS  Google Scholar 

  56. R. Friman, J. B. Rosenholm, Colloid Polym. Sci., 1982, 260, 545.

    Article  CAS  Google Scholar 

  57. T. L. Lin, S. H. Chen, N. Elise, N. E. Gabriel, M. F. Robers, J. Am. Chem. Soc., 1986, 108, 3499.

    Article  CAS  Google Scholar 

  58. Sz. Vass, J. Plestil, P. Laggner, T. Gilányi, S. Borbely, M. Kriechbaum, Gy. Jakli, Z. Decsy, P. M. Abuja, J. Phys. Chem. B., 2003, 107, 12752.

    Article  CAS  Google Scholar 

  59. G. V. Jensen, R. Lund, J. Gummel, T. Narayanan, J. S. Pedersen, Angew. Chem., Int. Ed. Engl., 2014, 53, 11524.

    Article  CAS  Google Scholar 

  60. J. W. Carvalho, F. R. Alves, T. Batista, F. A. O. Carvalho, P. S. Santiago, M. Tabak, Colloids Surf. B: Biointerfaces, 2013, 111, 561.

    Article  CAS  Google Scholar 

  61. J.-M. Lin, T.-L. Lin, U.-S. Jeng, Z.-H. Huang, Y.-S. Huang, Soft Matter, 2009, 5, 3913.

    Article  CAS  Google Scholar 

  62. M. Harada, K. Saijo, N. Sakamoto, H. Einaga, Colloids Surf. A, 2009, 345, 41.

    Article  CAS  Google Scholar 

  63. G. Colafemmina, D. Florentino, A. Ceglie, E. Carretti, E. Fratini, L. Dei, P. Baglioni, G. Palazzo, J. Phys. Chem. B, 2007, 111, 7184.

    Article  CAS  Google Scholar 

  64. M. Samsó, J.-R. Daban, S. Hansen, G. R. Jones, Eur. J. Biochem., 1995, 232, 818.

    Article  Google Scholar 

  65. S. F. Santos, D. Zanette, H. Fischer, R. Itri, J. Coll. Interface Sci., 2003, 262, 400.

    Article  CAS  Google Scholar 

  66. E. Y. Sheu, S.-H. Chen, J. Phys. Chem., 1988, 92, 4466.

    Article  CAS  Google Scholar 

  67. J. Narayanan, A. S. Abdul Rasheed, J. R. Bellare, J. Colloid Interface Sci., 208, 328, 67.

  68. S. F. Santos, D. Zanette, H. Fischer, R. Itri, J. Colloid Interface Sci., 2003, 262, 400.

    Article  CAS  Google Scholar 

  69. J. Marignan, P. Basserau, P. Delord, J. Phys. Chem., 1986, 90, 645.

    Article  CAS  Google Scholar 

  70. R. Itri, L. Q. Amaral, J. Phys. Chem., 1991, 95, 423.

    Article  CAS  Google Scholar 

  71. J. K. Percus, G. J. Yevick, Phys. Rev., 1958, 110, 1.

    Article  CAS  Google Scholar 

  72. J. P. Hansen, I. R. McDonald, Theory of Simple Liquids, Academic Press, London, 2006, 428 pp.

    Google Scholar 

  73. R. J. Baxter, J. Chem. Phys., 1968, 49, 2770.

    Article  CAS  Google Scholar 

  74. Y. C. Liu, S. H. Chen, J. S. Huang, Phys. Rev. E, 1996, 54, 1698.

    Article  CAS  Google Scholar 

  75. B. V. Deryagin, Teoriya ustoichivosti kolloidov i tonkikh plenok [Theory of Stable Colloids and Thin Films], Nauka, Moscow, 1986, 206 pp. (in Russian).

    Google Scholar 

  76. P. Stilbs, Prog. Nucl. Magn. Reson. Spectrosc., 1987, 19, 1.

    Article  CAS  Google Scholar 

  77. N. Muller, J. Phys. Chem., 1972, 76, 3017.

    Article  CAS  Google Scholar 

  78. J. Lang, C. Tondre, R. Zana, R. Bauer, H. Hoffmann, W. Ulbricht, J. Phys. Chem., 1975, 79, 276.

    Article  CAS  Google Scholar 

  79. M. Tokuyama, I. Oppenheim, Phys. Rev. E, 1994, 50, R16.

    Article  CAS  Google Scholar 

  80. V. D. Fedotov, Yu. F. Zuev, V. P. Archipov, Z. Sh. Idiyatullin, N. Garti, Colloids Surf. A, 1997, 128, 39.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center of the Russian Academy of Sciences, 8 ul. Arbuzova, 420088, Kazan, Russian Federation

    A. T. Gubaidullin, I. A. Litvinov & A. I. Samigullina

  2. Kazan State Power Engineering University, 51 ul. Krasnosel’skaya, 420066, Kazan, Russian Federation

    O. S. Zueva & V. S. Rukhlov

  3. Kazan Institute of Biochemistry and Biophysics, Kazan Scientific Center of the Russian Academy of Sciences, 2/31 ul. Lobachevskogo, 420111, Kazan, Russian Federation

    B. Z. Idiyatullin & Yu. F. Zuev

Authors
  1. A. T. Gubaidullin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. I. A. Litvinov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. I. Samigullina
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. O. S. Zueva
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. V. S. Rukhlov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. B. Z. Idiyatullin
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Yu. F. Zuev
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to I. A. Litvinov or Yu. F. Zuev.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 0158—0166, January, 2016

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Gubaidullin, A.T., Litvinov, I.A., Samigullina, A.I. et al. Structure and dynamics of concentrated micellar solutions of sodium dodecyl sulfate. Russ Chem Bull 65, 158–166 (2016). https://doi.org/10.1007/s11172-016-1278-2

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-016-1278-2

Keywords

Search

Navigation