Abstract
A method has been analyzed for calculating diffusion coefficients of 1 : 1 ionic surfactants as functions of their micellar solution concentrations within the framework of the quasi-chemical variant of the law of mass action. Relations have been presented for two- (with no allowance for micelles) and three-particle interaction (with allowance for micelles) formalisms. The methods for the introduction of initial calculation parameters and the calculation scheme for an ideal mixture of monomeric ions and micelles, as well as the correction for a deviation from ideality and a change in solution viscosity, have been considered. Numerical assessments have been performed by the examples of aqueous sodium dodecyl sulfate and alkyltrimethylammonium bromide solutions.
Similar content being viewed by others
References
Robinson, R. and Stoces, R., Electrolyte Solutions, London, 1959.
Sutherland, E., Mercer, S.M., Everist, M., and Leaist, D.G., J. Chem. Eng. Data, 2009, vol. 54, p. 272.
Movchan, T.G., Soboleva, I.V., Plotnikova, E.V., Shchekin, A.K., and Rusanov, A.I., Colloid J., 2012, vol. 74, p. 239.
Movchan, T.G., Shchekin, A.K., Soboleva, I.V., Khlebunova, N.R., Plotnikova, E.V., and Rusanov, A.I., Colloid J., 2015, vol. 77, p. 179.
Movchan, T.G., Rusanov, A.I., Soboleva, I.V., Khlebunova, N.R., Plotnikova, E.V., and Shchekin, A.K., Colloid J., 2015, vol. 77, p. 492.
Rusanov, A.I., Movchan, T.G., and Plotnikova, E.V., Colloid J., 2015, vol. 77, p. 507.
Rusanov, A.I., Colloid J., 2016, vol. 78, p. 102.
Leaist, D., J. Colloid Interface Sci., 1986, vol. 111, p. 230.
Evans, D.F., Mukherjee, S., Mitchell, D.J., and Ninham, B.W., J. Colloid Interface Sci., 1983, vol. 93, p. 184.
Kodama, M. and Miura, M., Bull. Chem. Soc. Jpn., 1972, vol. 45, p. 2265.
Lide, D.R., in CRC Handbook of Chemistry and Physics, p. 74.
Glasstone, S., Introduction to Electrochemistry, New York Van Nostrand, 1949.
Schwing, M., Bull. Union Phys., 2003, vol. 97, p. 323.
Rusanov, A.I., Mitselloobrazovanie v rastvorakh poverkhnostno-aktivnykh veshchestv (Micellization in Surfactant Solutions), St. Petersburg Khimiya, 1992.
Rusanov, A.I., Langmuir, 2014, vol. 30, p. 14443.
Lindman, B., Puyal, M.-C., Kamenka, N., Rumden, R., and Stilbs, P., J. Phys. Chem., 1984, vol. 88, p. 5048.
Rusanov, A.I., Colloid J., 2016, vol. 78, p. 669.
Rusanov, A.I., Colloid J., 2016, vol. 78, p. 733.
Cutler, S.G., Meares, P., and Hall, D.G., J. Chem. Soc., Faraday Trans. 1, 1978, vol. 74, p. 1758.
Lianos, P. and Zana, R., J. Colloid Interface Sci., 1981, vol. 84, p. 100.
Wasik, S.P. and Roscher, N.M., J. Phys. Chem., 1970, vol. 74, p. 2784.
Kryukova, G.N., Kasaikin, B.A., Sineva, A.V., and Markina, Z.N., Kolloidn. Zh., 1978, vol. 40, p. 457.
González-Pérez, A., Czapkiewicz, J., Prieto, G., and Rodriguez, J.R., Colloid Polym. Sci., 2003, vol. 281, p. 1191.
Gharibi, H., Palepu, R., Bloor, D.M., Hall, D.G., and Wyn-Jones, E., Langmuir, 1992, vol. 8, p. 782.
Markina, Z.N., Panicheva, L.P., and Zadymova, N.M., Colloid J., 1997, vol. 59, p. 315.
Durand-Vidal, S., Jardat, M., Dahirel, V., Bernard, O., Perrigaud, K., and Turq, P., J. Phys. Chem. B, 2006, vol. 110, p. 15542.
Basu Ray, G., Chakraborty, I., Ghosh, S., Moulik, S.P., Holgate, C., Glenn, K., and Palepu, R.M., J. Phys. Chem. B, 2007, vol. 111, p. 9828.
Villetti, M.A., Bica, C.I.D., Garcia, I.T.S., Pereira, F.V., Ziembowicz, F.I., Kloster, C.L., and Giacomelli, C., J. Phys. Chem. B, 2011, vol. 115, p. 5868.
Barry, B.W. and Russell, J.C., J. Colloid Interface Sci., 1972, vol. 40, p. 174.
Lee, Y.S. and Woo, K.W., Bull. Korean Chem. Soc., 1993, vol. 14, p. 392.
Bales, B. and Zana, R., J. Phys. Chem. B, 2002, vol. 106, p. 1926.
De Lisi, R., Fisicaro, E., and Milioto, S., J. Solution Chem., 1988, vol. 17, p. 1015.
Mirgorodskaya, A.B., Kudryavtseva, L.A., Vylegzhanina, N.N., Zuev, Yu.F., and Idiyatullin, B.Z., Kinet. Katal., 2005, vol. 46, p. 1.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © T.G. Movchan, A.I. Rusanov, E.V. Plotnikova, 2016, published in Kolloidnyi Zhurnal, 2016, Vol. 78, No. 6, pp. 750–759.
Rights and permissions
About this article
Cite this article
Movchan, T.G., Rusanov, A.I. & Plotnikova, E.V. Calculation aspects of diffusion coefficients in micellar solutions of ionic surfactants. Colloid J 78, 785–794 (2016). https://doi.org/10.1134/S1061933X16060107
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1061933X16060107