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Kinetics of direct and reverse polymorphic transformations in molecular crystals of energetic compounds

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Abstract

The β → γ polymorphic transformation (PT) in polycrystalline 1,1-diamino-2,2-dinitroethylene (DADNE) was studied by isothermal calorimetry. The kinetics of the β → γ PT, like that of the α → β process studied earlier, follows the first-order autocatalytic equation. The rate constants and activation energy of the process were determined. The kinetics of the reverse β → α and γ → α PTs in DADNE was studied by IR spectroscopy. The rates of the β → α and γ → α PTs follow first-order kinetics with the rate constants that depend on morphological features of the crystals. The general features of the kinetics of direct and reverse polymorphic transformations in molecular crystals of energetic compounds are discussed.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation

    V. V. Zakharov, N. V. Chukanov, A. D. Chervonnyi, S. V. Vozchikova & B. L. Korsunskii

  2. Xi’an Modern Chemistry Research Institute, 28 West Xianning Rd., The Building of Materials Science and Engineering, 710049, Xi’an, Shaanxi, China

    Yuanjie Shu & Zhiqun Chen

Authors
  1. V. V. Zakharov
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  2. N. V. Chukanov
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  3. A. D. Chervonnyi
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  4. S. V. Vozchikova
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  5. B. L. Korsunskii
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  6. Yuanjie Shu
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  7. Zhiqun Chen
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Correspondence to V. V. Zakharov.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 0091—0097, January, 2016.

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Zakharov, V.V., Chukanov, N.V., Chervonnyi, A.D. et al. Kinetics of direct and reverse polymorphic transformations in molecular crystals of energetic compounds. Russ Chem Bull 65, 91–97 (2016). https://doi.org/10.1007/s11172-016-1269-3

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  • DOI: https://doi.org/10.1007/s11172-016-1269-3

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