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Kinetics of reversible polymorphic transition in energetic materials. Phase transitions α → β and β → α in 1,1-diamino-2,2-dinitroethylene

  • Structure of Chemical Compounds. Spectroscopy
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Abstract

Differential scanning calorimetry and isothermal calorimetry are used to study the kinetics of the α → β polymorphic transformation (PT) in 1,1-diamino-2,2-dinitroethylene (DADNE). The kinetics of the β → α PT in DADNE is investigated by infrared spectrophotometry. The α → β phase transition is described by the first-order autocatalysis equation. The activation energy and the rate constant are determined. The rate of the β → α PT is described by the kinetic law for two parallel first-order processes. The rate constants for these processes are obtained.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow oblast, Russia

    V. V. Zakharov, N. V. Chukanov, A. D. Chervonnyi, S. A. Vozchikova & B. L. Korsounskii

Authors
  1. V. V. Zakharov
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  2. N. V. Chukanov
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  3. A. D. Chervonnyi
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  4. S. A. Vozchikova
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  5. B. L. Korsounskii
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Corresponding author

Correspondence to V. V. Zakharov.

Additional information

Original Russian Text © V.V. Zakharov, N.V. Chukanov, A.D. Chervonnyi, S.A. Vozchikova, B.L. Korsounskii, 2014, published in Khimicheskaya Fizika, 2014, Vol. 33, No. 11, pp. 47–54.

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Zakharov, V.V., Chukanov, N.V., Chervonnyi, A.D. et al. Kinetics of reversible polymorphic transition in energetic materials. Phase transitions α → β and β → α in 1,1-diamino-2,2-dinitroethylene. Russ. J. Phys. Chem. B 8, 822–828 (2014). https://doi.org/10.1134/S1990793114110104

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  • DOI: https://doi.org/10.1134/S1990793114110104

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