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Thermodynamics of the terpolymer of carbon monoxide, ethylene, and 1-butene

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Abstract

The heat capacity and the temperatures and enthalpies of physical transformations of the alternating terpolymer of carbon monoxide, ethylene, and 1-butene (the content of butene units is 10.7 mol.%) were studied by adiabatic and differential scanning calorimetry in the temperature range from 6 to 520 K. The energy of terpolymer combustion was measured at 298.15 K on an calorimeter with an isothermal shell and static bomb. The standard thermodynamic functions C°p(T), H°(T)–H°(0), S°(T)–S°(0), and G°(T)–H°(0) for the range from Т → 0 to 400 K, the standard enthalpy of combustion, and the thermodynamic parameters of formation of the partially crystalline CO—ethylene—1-butene terpolymer at 298.15 K, as well as the thermodynamic characteristics of its synthesis in the range from T → 0 to 400 K were calculated.

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Authors and Affiliations

  1. Lobachevsky State University of Nizhni Novgorod, 23/5 pr. Gagarina, 603950, Nizhny Novgorod, Russian Federation

    N. N. Smirnova, A. V. Markin, L. Ya. Tsvetkova, P. D. Afonin, O. N. Smirnova & E. A. Zakharychev

  2. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 18 Institutskii pr., 142432, Chernogolovka, Moscow region, Russian Federation

    O. N. Golodkov & G. P. Belov

Authors
  1. N. N. Smirnova
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  2. O. N. Golodkov
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  3. A. V. Markin
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  4. L. Ya. Tsvetkova
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  5. P. D. Afonin
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  6. O. N. Smirnova
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  7. E. A. Zakharychev
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  8. G. P. Belov
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Correspondence to N. N. Smirnova.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 0075—0081, January, 2016.

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Smirnova, N.N., Golodkov, O.N., Markin, A.V. et al. Thermodynamics of the terpolymer of carbon monoxide, ethylene, and 1-butene. Russ Chem Bull 65, 75–81 (2016). https://doi.org/10.1007/s11172-016-1267-5

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  • DOI: https://doi.org/10.1007/s11172-016-1267-5

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