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Rheological properties of nonfunctional derivatives of hyperbranched polycarbosilanes

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Abstract

The rheological properties of melts of nonfunctional hyperbranched polycarbosilane polymers differed in regularity of the structure and chain length between the branch points were studied for the first time. Unlike melts of linear polymers, the studied hyperbranched systems are Newtonian fluids, and the viscosity and activation energy of their viscous flow depend substantially on the molecular parameters and regularity of the molecular structure.

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Authors and Affiliations

  1. N. S. Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, 70 ul. Profsoyuznaya, 117393, Moscow, Russian Federation

    N. A. Sheremetyeva, V. D. Myakushev & A. M. Muzafarov

  2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    V. G. Vasiliev, V. S. Papkov, E. Yu. Kramarenko & A. M. Muzafarov

  3. M. V. Lomonosov Moscow State University of Fine Chemical Technologies, 86 prosp. Vernadskogo, 119571, Moscow, Russian Federation

    G. G. Pak

  4. Faculty of Physics, M. V. Lomonosov Moscow State University, Building 2, 1 Leninskie Gory, 119991, Moscow, Russian Federation

    E. Yu. Kramarenko

Authors
  1. N. A. Sheremetyeva
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  2. V. G. Vasiliev
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  3. V. S. Papkov
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  4. G. G. Pak
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  5. V. D. Myakushev
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  6. E. Yu. Kramarenko
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  7. A. M. Muzafarov
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Corresponding author

Correspondence to E. Yu. Kramarenko.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 2145–2151, September, 2015.

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Sheremetyeva, N.A., Vasiliev, V.G., Papkov, V.S. et al. Rheological properties of nonfunctional derivatives of hyperbranched polycarbosilanes. Russ Chem Bull 64, 2145–2151 (2015). https://doi.org/10.1007/s11172-015-1130-0

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  • DOI: https://doi.org/10.1007/s11172-015-1130-0

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