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Specific features of the chemical behavior of sodium 3,4,5-tris(2-thienyl)-1,2-diphosphacyclopentadienide

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Abstract

A new representative of 1,2-diphosphacyclopentadienide anions containing 2-thienyl substituents at carbon atoms was synthesized by the reaction of sodium polyphosphides with cyclopropenylphosphonium salts. The specific features of the chemical behavior of this compound were revealed by studying the reactions with organic and heteroorganic electrophiles and with pentacarbonylmanganese bromide.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation

    L. R. Kochetkova, I. A. Bezkishko, V. A. Miluykov, D. B. Krivolapov, O. N. Kataeva & O. G. Sinyashin

  2. A. M. Butlerov Chemical Institute, Kazan (Volga region) Federal University, 18 ul. Kremlevskaya, 420088, Kazan, Russian Federation

    D. R. Islamov

Authors
  1. L. R. Kochetkova
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  2. I. A. Bezkishko
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  3. V. A. Miluykov
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  4. D. R. Islamov
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  5. D. B. Krivolapov
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  6. O. N. Kataeva
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  7. O. G. Sinyashin
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Corresponding author

Correspondence to I. A. Bezkishko.

Additional information

Based on the materials of the XXVI International Chugaev Conference on Coordination Chemistry (October 6—10, 2014, Kazan).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1912—1918, August, 2015.

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Kochetkova, L.R., Bezkishko, I.A., Miluykov, V.A. et al. Specific features of the chemical behavior of sodium 3,4,5-tris(2-thienyl)-1,2-diphosphacyclopentadienide. Russ Chem Bull 64, 1912–1918 (2015). https://doi.org/10.1007/s11172-015-1093-1

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  • DOI: https://doi.org/10.1007/s11172-015-1093-1

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