Skip to main content
SpringerLink
Log in

Coordination compounds of DyIII and NdIII with malonic and succinic acid bispicolylamidrazones

  • Full Articles
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

Dysprosium(iii) and neodymium(iii) complexes with aliphatic dicarboxylic acid bispicolyl-amidrazones were synthesized and studied. X-ray diffraction data showed that the compounds under study have a binuclear structure, in which the coordination polyhedra are bound by two aliphatic bridges. When excited with UV radiation, neodymium complexes exhibit weak ionic photoluminescence, while no luminescent activity was shown by dysprosium complexes. The temperature dependence of magnetic susceptibility of dysprosium complexes was studied.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. C. Coulon, H. Miyasaka, R. Clérac, Structure and Bonding, 2006, 122, 163.

    Article  CAS  Google Scholar 

  2. S. Qiu, G. Zhu, Coord. Chem. Rev., 2009, 253, 2891.

    Article  CAS  Google Scholar 

  3. J.-P. Zhang, Y.-B. Zhang, J.-B. Lin, X.-M. Chen, Chem. Rev., 2012, 112, 1001.

    Article  CAS  Google Scholar 

  4. B. Moulton, M. J. Zaworotko, Curr. Opinion Solid State Mater. Sci., 2002, 6, 117.

    Article  CAS  Google Scholar 

  5. S. L. James, Chem. Soc. Rev., 2003, 32, 276.

    Article  CAS  Google Scholar 

  6. S. Decurtins, R. Pellaux, G. Antorrena, F. Palacio, Coord. Chem. Rev., 1999, 190—192, 841.

    Article  Google Scholar 

  7. G. M. Larin, V. V. Minin, V. F. Shul´gin, Russ. Chem. Rev., 2008, 77, 451.

    Article  CAS  Google Scholar 

  8. V. F. Shul´gin, A. N. Gusev, V. Ya. Zub, G. M. Larin, Russ. Chem. Bull. (Int. Ed.), 2002, 51, 2268 [Izv. Akad. Nauk, Ser. Khim., 2002, 2107].

    Article  Google Scholar 

  9. G. M. Larin, V. F. Shul´gin, A. N. Gusev, A. N. Chernega, Dokl. Chem. (Engl. Transl.), 2003, 390, 152 [Dokl. Akad. Nauk, 2003, 390, 627].

    CAS  Google Scholar 

  10. V. F. Shul´gin, A. N. Gusev, V. Ya. Zub, G. M. Larin, Russ. Chem. Bull. (Int. Ed.), 2005, 56, 1804 [Izv. Akad. Nauk, Ser. Khim., 2005, 1752].

    Article  Google Scholar 

  11. V. F. Shul´gin, A. N. Gusev, A. N. Chernega, G. M. Larin, Russ. Chem. Bull. (Int. Ed.), 2007, 56, 236 [Izv. Akad. Nauk, Ser. Khim., 2007, 229].

    Article  Google Scholar 

  12. O. V. Konnik, Z. Z. Bekirova, V. F. Shul´gin, S. B. Meshkova, P. G. Doga, S. S. Smola, G. G. Aleksandrov, I. L. Eremenko, Russ. J. Inorg. Chem. (Engl. Transl.), 2014, 59, 308 [Zh. Neorg. Khim., 2014, 59, 462].

    Article  CAS  Google Scholar 

  13. L. Zhao, V. Niel, L. K. Thompson, Z. Xu, V. A. Milway, R. G. Harvey, D. O. Miller, C. Wilson, M. Leech, J. A. K. Howard, S. L. Heath, Dalton Trans., 2004, 1446.

    Google Scholar 

  14. G. M. Sheldrick, SHELX97. Program for the Solution of Crystal Structures, Göttingen University, Göttingen (Germany), 1997.

    Google Scholar 

  15. Yu. V. Rakitin, V. T. Kalinnikov, Sovremennaya magnetokhimiya [Modern Magnetochemistry], Nauka, St.-Petersburg, 1994, 272 pp. (in Russian).

    Google Scholar 

  16. M. U. Anwar, S. S. Tandon, L. N. Dawe, F. Habib, M. Murugesu, L. K. Thompson, Inorg. Chem., 2012, 51, 1028.

    Article  CAS  Google Scholar 

  17. M. T. Gamer, Y. Lan, P. W. Roesky, A. K. Powell, R. Clerac, Inorg. Chem., 2008, 47, 6581.

    Article  CAS  Google Scholar 

  18. Y.-N. Guo, G.-F. Xu, Y. Guoa, J. Tang, Dalton Trans., 2011, 40, 9953.

    Article  CAS  Google Scholar 

  19. J. Tang, I. Hewitt, N. T. Madhu, G. Chastanet, W. Wernsdorfer, C. E. Anson, C. Benelli, R. Sessoli, A. K. Powell, Angew. Chem., Int. Ed., 2006, 45, 1729.

    Article  CAS  Google Scholar 

  20. D. N. Woodruff, R. E. P. Winpenny, R. A. Layfield, Chem. Rev., 2013, 113, 5110.

    Article  CAS  Google Scholar 

  21. Y.-L. Wang, Y. Ma, X. Yang, J. Tang, P. Cheng, Q.-L. Wang, L.-C. Li, D.-Z. Liao, Inorg. Chem., 2013, 52, 7380.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. V. I. Vernadsky Crimean Federal University, 4 prosp. Vernadskogo, 295007, Simferopol´, Republic of Crimea, Russian Federation

    A. N. Gusev & V. F. Shul´gin

  2. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    N. N. Efimov, V. V. Minin, G. G. Aleksandrov & I. L. Eremenko

Authors
  1. A. N. Gusev
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. F. Shul´gin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. N. N. Efimov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. V. Minin
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. G. G. Aleksandrov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. I. L. Eremenko
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. N. Gusev.

Additional information

Based on the materials of the XXVI International Chugaev Conference on Coordination Chemistry (October 6—10, 2014, Kazan).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1891—1895, August, 2015.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Gusev, A.N., Shul´gin, V.F., Efimov, N.N. et al. Coordination compounds of DyIII and NdIII with malonic and succinic acid bispicolylamidrazones. Russ Chem Bull 64, 1891–1895 (2015). https://doi.org/10.1007/s11172-015-1089-x

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-015-1089-x

Key words

Search

Navigation