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Cation-dependent spectral properties of fluorescent complexon based on 1,8-naphthalimide with PET mechanism of optical response

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Abstract

Complexation of 4-amino-1,8-naphthalimide derivative containing an aza-15-crown-5 ether receptor unit in the N-aryl substituent at the imide nitrogen atom of the naphthalimide core with alkaline earth metal cations was studied using optical and NMR spectroscopy. The binding of the cations with crown ether receptors was accompanied by signifacant fluorescence enhancement of naphthalimide moiety caused by the inhibition of the photoinduced electron transfer (PET) process. An increase in the cation radii on going from Mg2+ to Ca2+ to Ba2+ leads to a decrease in the complex stability and an increase in the quantum yield of its fluorescence.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    P. A. Panchenko, V. V. Park, O. A. Fedorova & Yu. V. Fedorov

  2. Faculty of Natural Sciences of Institute of Chemistry, Chemnitz University of Technology, 62 Strasse der Nation, D-09111, Chemnitz, Germany

    E. A. Kataev

Authors
  1. P. A. Panchenko
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  2. V. V. Park
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  3. O. A. Fedorova
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  4. Yu. V. Fedorov
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  5. E. A. Kataev
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Corresponding author

Correspondence to P. A. Panchenko.

Additional information

Based on the Materials of the XXVI International Chugaev Conference on Coordination Chemistry (October 6—10, 2014, Kazan).

Technische Universität Chemnitz, Fakultät für Naturwißsenschaften, Institut für Chemie, Straße der Nationen 62, D-09111 Chemnitz, Deutschland.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1871—1876, August, 2015.

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Panchenko, P.A., Park, V.V., Fedorova, O.A. et al. Cation-dependent spectral properties of fluorescent complexon based on 1,8-naphthalimide with PET mechanism of optical response. Russ Chem Bull 64, 1871–1876 (2015). https://doi.org/10.1007/s11172-015-1086-0

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  • DOI: https://doi.org/10.1007/s11172-015-1086-0

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