Skip to main content
SpringerLink
Log in

Studies of silicon nanocluster ligand coating by solid-state NMR

  • Full Articles
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

Silicon nanoclusters were studied by 29Si and 13C MAS NMR (magic angle spinning) spectroscopy. We for the first time confirmed the cleavage of ordinary ether C—O bonds of the solvent in the process of the synthesis of nanoclusters and the “binding” of the decomposition products to the surface of silicon nanoparticles as ligands. The applicability of MAS NMR spectroscopy in the studies of silicon nanocluster ligand coating and in the determination of the processes leading to the formation of the nanoparticle ligand shell was demonstrated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. V. G. Kuznetsov, P. A. Koz´min, Zh. Strukt. Khim., 1963, 4, 55 [J. Struct. Chem. (Engl. Transl.), 1963, 4].

    CAS  Google Scholar 

  2. J. A. Bertrand, F. A. Cotton, W. A. Dollase, J. Am. Chem. Soc., 1963, 85, 1349.

    Article  CAS  Google Scholar 

  3. M. N. Vargaftik, V. P. Zagorodnikov, I. P. Stolyarov, V. A. Likholobov, A. L. Chuvilin, V. I. Zaikovskii, D. I. Kochubei, G. I. Timofeeva, K. I. Zamaraev, I. I. Moiseev, Dokl. Akad. Nauk SSSR, 1985, 284, 896 [Dokl. Chem. (Engl. Transl.), 1985, 284].

    CAS  Google Scholar 

  4. X.-D. Wen, R. Hoffmann, N. W. Ashcroft, Adv. Mater., 2013, 25, 261.

    Article  CAS  Google Scholar 

  5. J. S. Son, X.-D. J. Wen, Joo, J. Chae, S. Baek, K. Park, J. H. Kim, K. An, J. H. Yu, S. G. Kwon, S.-H. Choi, Z. Wang, Y.-W. Kim, Y. Kuk, R. Hoffman, T. Hyeon, Angew. Chem. Int. Ed., 2009, 48, 6861.

    Article  CAS  Google Scholar 

  6. S. Ithurria, M. D. Tessier, B. Mahler, R. P. S. M. Lobo, B. Dubertret, A. L. Efros, Nat. Mater., 2011, 10, 936.

    Article  CAS  Google Scholar 

  7. J. Joo, J. S. Son, S. G. Kwon, J. H. Yu, T. Hyeon, J. Am. Chem. Soc., 2006, 128, 5632.

    Article  CAS  Google Scholar 

  8. C. Bouet, M. D. Tessier, S. Ithurria, B. Mahler, B. Nadal, B. Dubertret, Chem. Mater., 2013, 25, 1262.

    Article  CAS  Google Scholar 

  9. S. Ithurria, B. Dubertret, J. Am. Chem. Soc., 2008, 130, 16504.

    Article  CAS  Google Scholar 

  10. E. Cassette, B. Mahler, J.-M. Guigner, G. Patriarche, B. Dubertret, T. Pons, ACS Nano, 2012, 6, 6741.

    Article  CAS  Google Scholar 

  11. M. D. Tessier, C. Javaux, I. Maksimovic, V. Loriette, B. Dubertret, ACS Nano, 2012, 6, 6751.

    Article  CAS  Google Scholar 

  12. A. S. Orekhov, S. V. Savilov, V. N. Zakharov, A. V. Yatsenko, L. A. Aslanov, J. Nanopart. Res., 2014, 16, 2190.

    Article  Google Scholar 

  13. M. C. Beard, A. H. Ip, J. M. Luther, E. H. Sargent, A. J. Nozik, Quantum Confined Semiconductors for Enhancing Solar Photoconversion through Multiple Exciton Generation. in Advanced Concepts in Photovoltaics, Eds A. J. Nozik, G. Conibeer, M. C. Beard, RCS, Cambridge, 2014, p.345.

  14. D. Mayeri, B. L. Phillips, M. P. Augustine, S. M. Kauzlarich, Chem. Mater., 2001, 13, 765.

    Article  CAS  Google Scholar 

  15. R. K. Baldwin, K. A. Pettigrew, E. Ratai, M. P. Augustine, S. M. Kauzlarich, Chem. Commun., 2002, 1822.

    Google Scholar 

  16. R. A. Faulkner, J. A. DiVerdi, Y. Yang, T. Kobayashi, G. E. Maciel, Materials, 2013, 6, 18.

    Article  CAS  Google Scholar 

  17. J. M. Schmeltzer, L. A. Porter, M. P. Stewart, J. M. Buriak, Langmuir, 2002, 18, 2971.

    Article  CAS  Google Scholar 

  18. A. S. Heintz, M. J. Fink, B. S. Mitchell, Adv. Mater., 2007, 19, 3984.

    Article  CAS  Google Scholar 

  19. J. R. Giuliani, S. J. Harley, R. S. Carter, P. P. Power, M. P. Augustine, Solid State Nuclear Magnetic Resonance, 2007, 32, 1.

    Article  CAS  Google Scholar 

  20. R. S. Carter, S. J. Harley, P. P. Power, M. P. Augustine, Chem. Mater., 2005, 17, 2932.

    Article  CAS  Google Scholar 

  21. R. L. Cook, Anal. Bioanal. Chem., 2004, 378, 1484.

    Article  CAS  Google Scholar 

  22. G. Metz, X. L. Wu, S. O. Smith, J. Magn. Reson. Ser. A, 1994, 110, 219.

    Article  CAS  Google Scholar 

  23. R. S. Thakur, N. D. Kurur, P. K. Madhu, Chem. Phys. Lett., 2006, 426, 459.

    Article  CAS  Google Scholar 

  24. L. A. Aslanov, V. N. Zakharov, A. V. Pavlikov, S. V. Savilov, V. Yu. Timoshenko, A. V. Yatsenko, Russ. J. Coord. Chem. (Engl. Transl.), 2013, 39, 427 [Koord. Khim., 2013, 39, 323].

    Article  CAS  Google Scholar 

  25. A. S. Orekhov, S. V. Savilov, V. N. Zakharov, A. V. Yatsenko, L. A. Aslanov, Russ. J. Coord. Chem. (Engl. Transl.), 2014, 40, 1 [Koord. Khim., 2014, 40, 3].

    Article  CAS  Google Scholar 

  26. H. Coffn, C. Bonafos, S. Schamm, N. Cherkashin, G. Ben Assayag, A. Claverie, M. Respaud, P. Dimitrakis, P. Normand, J. Appl. Phys., 2006, 99, 044302.

    Article  Google Scholar 

  27. G. Engelhardt, D. Michel, High resolution Solid-State NMR of Silicates and Zeolites, Wiley, Chichester, 1987, 485 pp.

    Google Scholar 

  28. K. R. Carduner, R. O. Carter III, M. E. Milberg, G. M. Crosbie, Anal. Chem., 1987, 59, 2794.

    Article  CAS  Google Scholar 

  29. J. W. Kriesel, T. Don Tilley, Chem. Mater., 2000, 12, 1171.

    Article  CAS  Google Scholar 

  30. J. A. Chaker, C. V. Santilli, S. H. Pulcinelli, K. Dahmouche, V. Brioisb, P. Judeinstein, J. Mater. Chem., 2007, 17, 744.

    Article  CAS  Google Scholar 

  31. A. Shimojima, R. Goto, N. Atsumi, K. Kuroda, Chem. Eur. J., 2008, 14, 8500.

    Article  CAS  Google Scholar 

  32. Y. Kaneko, N. Iyi, T. Matsumoto, H. Usami, J. Mater. Res., 2005, 20, 2199.

    Article  CAS  Google Scholar 

  33. A. Shimojima, H. Kuge, K. Kuroda, Sol-Gel Sci. Technol., 2011, 57, 263.

    Article  CAS  Google Scholar 

  34. Y. Mito-oka, S. Horike, Y. Nishitani, T. Masumori, M. Inukai, Y. Hijikata, S. Kitagawa, J. Mater. Chem. A, 2013, 1, 7885.

    Article  CAS  Google Scholar 

  35. Z. Olejniczaka, M. Leczka, K. Cholewa-Kowalska, K. Wojtach, M. Rokita, W. Mozgawa, J. Mol. Struct., 2005, 744—747, 465.

    Article  Google Scholar 

  36. N. M. Scully, L. O. Healy, T. O´Mahony, J. D. Glennon, B. Dietrich, K. Albert, J. Chromatogr. A, 2008, 1191, 99.

    Article  CAS  Google Scholar 

  37. U. Diaz-Morales, G. Bellussi, A. Carati, R. Millini, W.O´N. Parker, C. Rizzo, Micropor. Mesopor. Mater., 2006, 87, 185.

    Article  CAS  Google Scholar 

  38. F. Adam, H. Osman, K. M. Hello, J. Coll. Interface Sci., 2009, 331, 143.

    Article  CAS  Google Scholar 

  39. S. Chen, S. Hayakawa, Y. Shirosaki, E. Fujii, K. Kawabata, K. Tsuru, A. Osaka, J. Am. Ceram. Soc., 2009, 92, 2074.

    Article  CAS  Google Scholar 

  40. G. I. Dobryanskaya, I. V. Mel´nik, Yu. L. Zub, A. Dabrowski, Russ. J. Phys. Chem. A (Engl. Transl.), 2007, 81, 339 [Zh. Fiz. Khim., 2007, 81, 410].

    Article  CAS  Google Scholar 

  41. E. Lindner, R. Schreiber, M. Kemmler, T. Schneller, H. A. Mayer, Chem. Mater., 1995, 7, 951.

    Article  CAS  Google Scholar 

  42. M. Jaber, J. Miehe-Brendle, M. Roux, J. Dentzer, R. Le Dred, J.-L. Guth, New J. Chem., 2002, 26, 1597.

    Article  CAS  Google Scholar 

  43. B. A. Ashu-Arrah, J. D. Glennon, K. Albert, J. Chromatogr. A, 2013, 1298, 86.

    Article  CAS  Google Scholar 

  44. S. Tahara, Y. Takeda, Y. Sugahara, Chem. Mater., 2005, 17, 6198.

    Article  CAS  Google Scholar 

  45. H. E. Gottlieb, V. Kotlyar, A. Nudelman, J. Org. Chem., 1997, 62, 7512.

    Article  CAS  Google Scholar 

  46. SciFinder: CAS Registry Number 125437-38-9; Spectrum ID 125437389-CNMR.

  47. A. Kamyshny, V. N. Zakharov, M. A. Zakharov, A. V. Yatsenko, S. V. Savilov, L. A. Aslanov, S. Magdassi, J. Nanopart. Res., 2011, 13, 1971.

    Article  CAS  Google Scholar 

  48. L. A. Aslanov, V. N. Zakharov, M. A. Zakharov, A. L. Kamyshnyi, Sh. Magdassi, A. V. Yatsenko, Russ. J. Coord. Chem. (Engl. Transl.), 2010, 36, 330 [Koord. Khim., 2010, 36, 330].

    Article  CAS  Google Scholar 

  49. Q. Liu, S. M. Kauzlarich, Materials Science and Engineering, 2002, B96, 72.

    Article  CAS  Google Scholar 

  50. J. Zou, P. Sanelle, K. A. Pettigrew, S. M. Kauzlarich, J. Cluster Sci., 2006, 17, 565.

    Article  CAS  Google Scholar 

  51. U. Azzena, G. Dettori, I. Mascia, L. Pisano, M. Pittalis, Tetrahedron, 2007, 63, 11998.

    Article  CAS  Google Scholar 

  52. Z. Grobelny, A. Stolarzewicz, A. Maercker, S. Krompiec, J. Kasperczyk, J. Rzepa, J. Organomet. Chem., 2004, 689, 1580.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, M. V. Lomonosov Moscow State University, Build. 3, 1 Leninskie Gory, 119991, Moscow, Russian Federation

    Yu. G. Kolyagin, V. N. Zakharov, A. V. Yatsenko & L. A. Aslanov

Authors
  1. Yu. G. Kolyagin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. N. Zakharov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. V. Yatsenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. L. A. Aslanov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to L. A. Aslanov.

Additional information

Based on the materials of the XXVI International Chugaev Conference on Coordination Chemistry (October 6—10, 2014, Kazan).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1829—1832, August, 2015.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kolyagin, Y.G., Zakharov, V.N., Yatsenko, A.V. et al. Studies of silicon nanocluster ligand coating by solid-state NMR. Russ Chem Bull 64, 1829–1832 (2015). https://doi.org/10.1007/s11172-015-1079-z

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-015-1079-z

Key words

Search

Navigation