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Cobalt(II) complexes with bis-2,4-[N-(S)-phenylalanyl]-6-chlorotriazine: synthesis, structure, and application for separation of enantiomers of butan-2-ol

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Abstract

The chiral coordination compounds [Co(L)(H2O)2(MeOH)] n (1) and Co2(L)2(H2O)(MeOH)4 (2) were synthesized by the reaction of bis-2,4-[N-(S)-phenylalanyl]6-chlorotriazine (LH2) with cobalt(II) pivalate or acetate. In molecules 2, the CoII ions are linked by a bridging water molecule and two carboxy groups of the L2– anion. By passing the racemate of butan-2-ol through a chromatographic column containing complex 1 as the stationary phase, a mixture enriched with the (S)-isomer of this alcohol can be obtained.

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Authors and Affiliations

  1. L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, 31 prosp. Nauki, 03028, Kiev, Ukraine

    Yu. A. Satskaya & S. V. Kolotilov

  2. Enamine Ltd., 61 Chervonotkaska ul., 03022, Kiev, Ukraine

    N. P. Komarova, K. S. Gavrilenko & O. V. Manoylenko

  3. ChembioCenter, Taras Shevchenko National University of Kyiv, 61 Chervonotkackaya ul., 03022, Kiev, Ukraine

    K. S. Gavrilenko & O. V. Manoylenko

  4. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    M. A. Kiskin, I. L. Eremenko & V. M. Novotortsev

Authors
  1. Yu. A. Satskaya
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  2. N. P. Komarova
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  3. K. S. Gavrilenko
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  4. O. V. Manoylenko
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  5. M. A. Kiskin
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  6. S. V. Kolotilov
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  7. I. L. Eremenko
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  8. V. M. Novotortsev
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Corresponding author

Correspondence to M. A. Kiskin.

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Dedicated to Academician of the Russian Academy of Sciences V. I. Minkin on the occasion of his 80th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 0630—0635, March, 2015.

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Satskaya, Y.A., Komarova, N.P., Gavrilenko, K.S. et al. Cobalt(II) complexes with bis-2,4-[N-(S)-phenylalanyl]-6-chlorotriazine: synthesis, structure, and application for separation of enantiomers of butan-2-ol. Russ Chem Bull 64, 630–635 (2015). https://doi.org/10.1007/s11172-015-0910-x

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  • DOI: https://doi.org/10.1007/s11172-015-0910-x

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