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Synthesis of a tetranuclear mixed-ligand CoII complex with pivalate and acetate

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Abstract

When studying the synthesis of NBu4[Co(piv)3] and NBu4[Cu(piv)3], where NBu4 is a tetrabutylammonium cation and piv is a pivalate anion, in some cases we obtained a few crystals of the tetranuclear complexes (NBu4)2[M4(piv)8(AcO)2(H2O) n ], where M = Co, n = 4; M = Cu, n = 2, AcO is the acetate anion. These complexes contain only deprotonated pivalate and acetate anions as coordinated organic ligands and represent a rare type of polynuclear compounds, which have not been obtained earlier as the major individual phase. For CoII, a method was developed for the straightforward synthesis of the complex (NBu4)2[Co4(piv)8(AcO)2(H2O)4].

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Authors and Affiliations

  1. International Tomography Center, Siberian Branch of the Russian Academy of Sciences, 3a ul. Institutskaya, 630090, Novosibirsk, Russian Federation

    E. Yu. Fursova, G. V. Romanenko, R. Z. Sagdeev & V. I. Ovcharenko

Authors
  1. E. Yu. Fursova
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  2. G. V. Romanenko
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  3. R. Z. Sagdeev
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  4. V. I. Ovcharenko
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Corresponding author

Correspondence to V. I. Ovcharenko.

Additional information

Dedicated to Academician of the Russian Academy of Sciences V. I. Minkin on the occasion of his 80th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 0626—0629, March, 2015.

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Fursova, E.Y., Romanenko, G.V., Sagdeev, R.Z. et al. Synthesis of a tetranuclear mixed-ligand CoII complex with pivalate and acetate. Russ Chem Bull 64, 626–629 (2015). https://doi.org/10.1007/s11172-015-0909-3

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  • DOI: https://doi.org/10.1007/s11172-015-0909-3

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