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Microporous coordination polymer [Zn4(dmf)(ur)2(ndc)4] as a heterogeneous catalyst for the Knoevenagel reaction

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Abstract

The catalytic properties of the microporous metal-organic coordination polymer [Zn4(dmf)(ur)2(ndc)4] (dmf is N,N’-dimethylformamide, ur is urotropine, and ndc2- is 2,6-naphthalenedicarboxylate) for the Knoevenagel reaction were studied. The reaction between aromatic aldehydes (benzaldehyde, α-naphthaldehyde, 4-biphenylaldehyde, and 1-pyrenaldehyde) and malononitrile was studied. The coordination polymer was shown to be a heterogeneous catalyst that makes it possible to achieve 95% yield in the reaction between benzaldehyde and malononitrile. The selectivity of the catalyst depends on the size of aldehydes used in the reaction.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrent’eva, 630090, Novosibirsk, Russian Federation

    S. A. Sapchenko, D. N. Dybtsev & V. P. Fedin

  2. Novosibirsk State University, 2 ul. Pirogova, 630090, Novosibirsk, Russian Federation

    S. A. Sapchenko, D. N. Dybtsev & V. P. Fedin

Authors
  1. S. A. Sapchenko
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  2. D. N. Dybtsev
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  3. V. P. Fedin
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Correspondence to V. P. Fedin.

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Dedicated to Academician of the Russian Academy of Sciences Yu. N. Bubnov on the occasion of his 80 birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2363–2368, October, 2014.

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Sapchenko, S.A., Dybtsev, D.N. & Fedin, V.P. Microporous coordination polymer [Zn4(dmf)(ur)2(ndc)4] as a heterogeneous catalyst for the Knoevenagel reaction. Russ Chem Bull 63, 2363–2368 (2014). https://doi.org/10.1007/s11172-014-0748-7

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  • DOI: https://doi.org/10.1007/s11172-014-0748-7

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