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Modified graphene oxide as a support for rhodium nanoparticles active in olefin hydroformylation

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Abstract

A new two-step procedure for modifying graphene oxide by the methylation of its surface with trimethyl-o-formate followed by the treatment with methyl iodide was developed. The methylation product was used as a support for the formation of rhodium nanoparticles. The obtained samples of graphene oxide containing rhodium nanoparticles were characterized by IR spectroscopy, X-ray fluorescence spectroscopy, and transmission electron microscopy. The Rh-containing nanocomposites were used as atalysts for the hydroformylation of olefins in upercritical carbon dioxide and organic solvents.

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    Yu. V. Ioni & S. P. Gubina

  2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    S. E. Lyubimov & V. A. Davankov

Authors
  1. Yu. V. Ioni
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  2. S. E. Lyubimov
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  3. V. A. Davankov
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  4. S. P. Gubina
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Corresponding author

Correspondence to Yu. V. Ioni.

Additional information

Dedicated to Academician of the Russian Academy of Sciences Yu. N. Bubnov on the occasion of his 80 birthday and to the 60th anniversary of the foundation A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2243–2249, October, 2014.

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Ioni, Y.V., Lyubimov, S.E., Davankov, V.A. et al. Modified graphene oxide as a support for rhodium nanoparticles active in olefin hydroformylation. Russ Chem Bull 63, 2243–2249 (2014). https://doi.org/10.1007/s11172-014-0729-x

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  • DOI: https://doi.org/10.1007/s11172-014-0729-x

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