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A One-Step Method for Preparation of Ru Nanoparticle Decorated on Three-Dimensional Graphene with High Catalytic Activity for Reduction of Nitroarenes

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Abstract

Ruthenium nanoparticles on nitrogen and sulfur-doped three-dimensional graphene (Ru@NSG) nanohybrid were prepared via a one-pot hydrothermal method with graphene oxide (GO) and RuCl3 as the raw materials and thiourea as a reducing-doping agent for the first time. The catalytic activity of nanohybrid was evaluated by the reduction of nitroarenes to the corresponding anilines. The effect of the weight ratio of Ru/GO was evaluated on catalytic activity. Moreover, in order to prove the role of the heteroatom substitution in graphene lattice, the Ru@NG and Ru@G hybrids were synthesized, and it was shown that the reaction yields would decrease in the presence of Ru@NG and Ru@G hybrids.

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Acknowledgements

This work was supported by Research Council of Shahid Beheshti University.

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Authors and Affiliations

  1. Faculty of Chemistry and Petroleum Sciences, Shahid Beheshti University, District 1, Daneshjou Boulevard, 1983969411, Tehran, Tehran Province, Iran

    Minoo Dabiri, Seyedesahar Miraghaee & Roonak Nikbakht

  2. Sydney Medical School, The University of Sydney, Sydney, Australia

    Sahareh Bashiribod

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  1. Minoo Dabiri
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  2. Seyedesahar Miraghaee
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  3. Roonak Nikbakht
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  4. Sahareh Bashiribod
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Correspondence to Minoo Dabiri.

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Dabiri, M., Miraghaee, S., Nikbakht, R. et al. A One-Step Method for Preparation of Ru Nanoparticle Decorated on Three-Dimensional Graphene with High Catalytic Activity for Reduction of Nitroarenes. J Clust Sci 32, 959–965 (2021). https://doi.org/10.1007/s10876-020-01860-1

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  • DOI: https://doi.org/10.1007/s10876-020-01860-1

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