Abstract
New complexes of 1,1′-bisisoquinoline with PdCl2 and NiCl2 were synthesized. The structures of the complexes were established by X-ray diffraction. The Pdii complex acts as a catalyst for the Suzuki and Heck reactions and the hydroarylation of norbornene. As exemplified by the Suzuki reaction, the Niii complex can also be used as a catalyst.
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According to the materials of the International Conference “Organometallic and Coordination Chemistry: Fundamental and Applied Aspects” (September 1–7, 2013, Nizhny Novgorod).
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 0883–0889, April, 2014.
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Khrushcheva, N.S., Bulygina, L.A., Starikova, Z.A. et al. Synthesis, structure, and catalytic activity of complexes of 1,1′-bisisoquinoline with PdCl2 and NiCl2 . Russ Chem Bull 63, 883–889 (2014). https://doi.org/10.1007/s11172-014-0524-8
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DOI: https://doi.org/10.1007/s11172-014-0524-8