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Synthesis, crystal structure, and physicochemical properties of the new metal-organic framework — the iron(iii) complex with benzene-1,3,5-tricarboxylate

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Abstract

A new iron(iii) coordination compound with the benzene-1,3,5-tricarboxylate anion of the composition [Feiii 2(OH)0.3(H2O)1.7(btc)4/3]Cl1.7·2.8DMF·1.9H2O (1) was synthesized. Its crystal structure was determined, and the Mössbauer spectra were analyzed. The adsorption of salicylaldehyde and nitromethane by compound 1 was studied. The adsorption kinetics of salicylaldehyde is described by the pseudo-second order equation. The diffusion of this aldehyde in particles of compound 1 is, most probably, the rate-limiting step in the Henry reaction.

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Authors and Affiliations

  1. L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, 31 prosp. Nauki, 03028, Kiev, Ukraine

    S. A. Sotnik, S. V. Kolotilov & V. V. Pavlishchuk

  2. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    M. A. Kiskin, Zh. V. Dobrokhotova, V. M. Novotortsev & I. L. Eremenko

  3. Chembio Center, National Taras Shevchenko University of Kyiv, 61 ul. Chervonotkattskaya, 03022, Kiev, Ukraine

    K. S. Gavrilenko

  4. N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 4 ul. Kosygina, 119991, Moscow, Russian Federation

    V. K. Imshennik & Yu. V. Maksimov

Authors
  1. S. A. Sotnik
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  2. S. V. Kolotilov
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  3. M. A. Kiskin
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  4. Zh. V. Dobrokhotova
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  5. K. S. Gavrilenko
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  6. V. M. Novotortsev
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  7. I. L. Eremenko
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  8. V. K. Imshennik
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  9. Yu. V. Maksimov
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  10. V. V. Pavlishchuk
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Corresponding author

Correspondence to S. A. Sotnik.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 0862–0869, April, 2014.

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Sotnik, S.A., Kolotilov, S.V., Kiskin, M.A. et al. Synthesis, crystal structure, and physicochemical properties of the new metal-organic framework — the iron(iii) complex with benzene-1,3,5-tricarboxylate. Russ Chem Bull 63, 862–869 (2014). https://doi.org/10.1007/s11172-014-0522-x

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  • DOI: https://doi.org/10.1007/s11172-014-0522-x

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