Abstract
The temperature dependence of heat capacity of triple alternating copolymer ethylene—carbon monoxide—propylene with 23.4 mol.% of propane fragments was studied for the first time by adiabatic and dynamic calorimetry over the range of 6–480 K. The energy of copolymer combustion at 298.15 K was measured in isothermic calorimeter with stationary bomb. The thermodynamic parameters of phase and physical transitions were determined. The standard thermodynamic functions C p ○(T), H ○(T) − H ○(0), S ○(T) − S ○(0) and G ○(T) − H ○(0), for region from T→ 0 to 320 K, the standard enthalpy of combustion and thermodynamic characteristics of formation of the studied compound at 298.15 K were calculated from the experimental data. The thermodynamic parameters of alternating copolymerization of CO with ethylene and propylene at standard pressure over 0–300 K region were detemined.
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References
E. Drent, P. M. Budzelaar, Chem. Rev., 1996, 96, 663.
G. P. Belov, E. V. Novikova, Russ. Chem. Rev., 2004, 73, 267.
B. V. Lebedev, K. B. Zhogova, Ya. V. Denisova, G. P. Belov, O. N. Golodkov, Russ. Chem. Bull. (Engl. Transl.), 1998, 47, 277 [Izv. Akad. Nauk, Ser. Khim., 1998, 284].
B. V. Lebedev, A. V. Tsvetkova, N. N. Smirnova, G. P. Belov, O. N. Golodkov, Yu. A. Kurskii, Russ. Chem. Bull. (Engl. Transl.), 1999, 48, 1507 [Izv. Akad. Nauk, Ser. Khim., 1999, 1527].
A. V. Arapova, B. V. Lebedev, N. N. Smirnova, T. G. Kulagina, G. P. Belov, O. N. Golodkov, Russ. Chem. Bull. (Int. Ed.), 2001, 50, 2372 [Izv. Akad. Nauk, Ser. Khim., 2001, 2264].
T. A. Bykova, N. N. Smirnova, G. P. Belov, E. V. Novikova, Vysokomolekulyar. Soedin., Ser. B, 2004, 46, 374 [Polym. Sci., Ser. B (Engl. Transl.), 2004, 46].
T. A. Bykova, N. N. Smirnova, T. G. Kulagina, L. V. Nikishchenkova, G. P. Belov, E. V. Novikova, Russ. Chem. Bull. (Int. Ed.), 2005, 54, 1527 [Izv. Akad. Nauk, Ser. Khim., 2005, 1483].
N. N. Smirnova, L. V. Nikishchenkova, T. A. Bykova, T. G. Kulagina, G. P. Belov, E. V. Novikova, Thermochim. Acta, 2006, 451, 156.
J. M. Lagaron, M. E. Vickers, A. K. Powell, N. S. Davidson, Polymer, 2000, 41, 3011.
G. P. Belov, E. G. Chepaikin, A. P. Bezruchenko, V. I. Smirnov, Vysokomolekulyar. Soedin., Ser. A, 1993, 35, 1585 [Polym. Sci., Ser. A (Engl. Transl.), 1993, 35].
R. M. Varushchenko, A. I. Druzhinina, E. L. Sorkin, J. Chem. Thermodyn., 1997, 29, 623.
V. M. Malyshev, G. A. Milner, E. L. Sorkin, V. F. Shibakin, Pribory i tekhnika eksperimenta [Instruments and Experimental Techniques], 1985, 6, 195 (in Russian).
G. W. H. Hohne, W. F. Hemminger, H. F. Flammersheim, Differential Scanning Calorimetry, Springer-Verlag, Berlin-Heidelberg, 2003, 299.
V. A. Drebushchak, J. Therm. Anal. Calorim., 2005, 79, 213.
B. V. Lebedev, E. G. Kiparisova, Zh. Fiz. Khim., 1996, 70, 1351 [J. Phys. Chem. (Engl. Transl.), 1996, 70].
S. Alford, M. Dole, J. Am. Chem. Soc., 1955, 77, 4774.
G. Adam, J. U. Gibbs, J. Chem. Phys., 1965, 43, 139.
W. Kauzmann, Chem. Rew., 1948, 43, 218.
B. J. Lommerts, E. A. Klop, J. Aerts, J. Polym. Sci. B: Polym. Phys., 1993, 31, 1319.
B. J. Lommerts, Structure Development in Polyalchol Fibers, Rijksuniversitetit Groninger, Netherland, 1960, 131.
B. V. Lebedev, N. N. Smirnova, Khimicheskaya termodinamika polialkanov i polialkenov [Chemical Thermodynamics of Polyalkanes and Polyalkenes], Izd-vo Nizhegorodskogo Gos. Un-ta. Nizhny Novgorod, 1999, 274 (in Russian).
B. V. Lebedev, I. B. Rabinovich, Dokl. Akad. Nauk SSSR, [Dokl. Chem. (Engl. Transl.), 1977].
B. V. Lebedev, Thermochim. Acta, 1997, 297, 143.
J. D. Cox, D. D. Wagman, V. A. Medvedev, Codata Key Values for Thermodynamics, Hemisphere Publishing Corp., New York, 1984.
M. W. Chase, Jr., J. Phys. Chem. Ref. Data, Monograph, 1998, 9, 1951.
Termicheskie konstanty veshchestv [Thermal Constants of Substances], Ed. V. P. Glushko, VINITI, Moscow, 1965–1972, Iss. 1–6 (in Russian).
K. A. Kobe, R. E. Lynn, Chem. Rev., 1953, 52, 117.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 0621–0626, March, 2014.
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Smirnova, N.N., Kozlova, M.S., Golodkov, O.N. et al. Thermodynamics of triple alternating copolymer ethylene—carbon monoxide—propylene. Russ Chem Bull 63, 621–626 (2014). https://doi.org/10.1007/s11172-014-0483-0
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DOI: https://doi.org/10.1007/s11172-014-0483-0