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Synthesis and properties of carbosilane dendrimers of the third and sixth generations with the ethylene oxide surface layer in bulk and in monolayers at the air-water interface

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Abstract

A number of carbosilane dendrimers with the ethylene oxide surface layer was synthesized. The density of the surface layer determines their capability to form a physical network due to intermolecular entanglements. The specific interactions of the ethylene oxide fragments exert a minor effect on the thermal behavior of dendritic macromolecules. The compression-expansion isotherms of Langmuir films together with Brewster angle microscopy data show that an increase in the core rigidity with increasing the generation number favors the formation of ordered molecular multilayers. The appearance of a pronounced hysteresis in the compression-expansion cycles is a common phenomenon for amphiphilic dendrimers of high generations.

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References

  1. D. Astruc, E. Boisselier, C. Ornelas, Chem. Rev., 2010, 110, 1857.

    Article  CAS  Google Scholar 

  2. L. M. Bronstein, Z. B. Shifrina, Chem. Rev., 2011, 111, 5301.

    Article  CAS  Google Scholar 

  3. X. Peng, Q. Pan, G. L. Rempel, Chem. Soc. Rev., 2008, 37, 1619

    Article  Google Scholar 

  4. P. G. de Gennes, H. Hervet, J. Phys. Lett., 1983, 44, 351.

    Article  Google Scholar 

  5. E. A. Tatarinova, E. A. Rebrov, V. D. Myakushev, I. B. Meshkov, N. V. Demchenko, A. V. Bystrova, O. V. Lebedeva, A. M. Muzafarov, Russ. Chem. Bull. (Int. Ed.), 2004, 53, 2591 [Izv. Akad. Nauk, Ser. Khim., 2004, 2484].

    Article  CAS  Google Scholar 

  6. A. M. Muzafarov, E. A. Rebrov, J. Polym. Sci., Part A: Polym. Chem., 2008, 46, 4935.

    Article  CAS  Google Scholar 

  7. N. N. Smirnova, O. V. Stepanova, T. A. Bykova, A. V. Markin, A. M. Muzafarov, E. A. Tatarinova, V. D. Myakushev, Thermochim. Acta, 2006, 440, 188.

    Article  CAS  Google Scholar 

  8. N. N. Smirnova, O. V. Stepanova, T. A. Bykova, A. V. Markin, E. A. Tatarinova, A. M. Muzafarov, Russ. Chem. Bull. (Int. Ed.), 2007, 56, 1991 [Izv. Akad. Nauk, Ser. Khim., 2007, 1924].

    Article  CAS  Google Scholar 

  9. A. S. Tereshchenko, G. S. Tupitsyna, E. A. Tatarinova, A. V. Bystrova, A. M. Muzafarov, N. N. Smirnova, A. V. Markin, Polym. Sci., Ser. B (Engl. Transl.), 2010, 52, 41 [Vysokomol. Soedin., Ser. B, 2010, 52, 132].

    Article  Google Scholar 

  10. N. N. Smirnova, A. V. Markin, Ya. S. Samosudova, G. M. Ignat’eva, A. M. Muzafarov, Russ. J. Phys. Chem. A (Engl. Transl.), 2010, 84, 784 [Zh. Fiz. Khim., 2010, 84, 884].

    Article  CAS  Google Scholar 

  11. N. N. Smirnova, A. V. Markin, Ya. S. Samosudova, G. M. Ignat’eva, E. Yu. Katarzhnova, A. M. Muzafarov, Russ. J. Phys. Chem. A (Engl. Transl.), 2013, 87, 552 [Zh. Fiz. Khim., 2013, 87, 570].

    Article  CAS  Google Scholar 

  12. A. I. Kuklin, A. N. Ozerin, A. Kh. Islamov, A. M. Muzafarov, V. I. Gordeliy, E. A. Rebrov, G. M. Ignat’eva, E. A. Tatarinova, R. I. Mukhamedzyanov, L. A. Ozerina, E. Yu. Sharipov, J. Appl. Crystallogr., 2003, 36, 679.

    Article  CAS  Google Scholar 

  13. M. V. Mironova, A. V. Semakov, A. S. Tereshchenko, E. A. Tatarinova, E. V. Getmanova, A. M. Muzafarov, V. G. Kulichikhin, Polym. Sci., Ser. A (Engl. Transl.), 2010, 52, 1156 [Vysokomol. Soedin., Ser. A, 2010, 52, 1960].

    Article  Google Scholar 

  14. A. M. Muzafarov, N. G. Vasilenko, E. A. Tatarinova, G. M. Ignat’eva, V. D. Myakushev, M. A. Obrezkova, I. B. Meshkov, N. V. Voronina, O. V. Novozhilov, Polym. Sci., Ser. C (Engl. Transl.), 2011, 53, 48 [Vysokomol. Soedin., Ser. C, 2011, 53, 1217].

    Article  CAS  Google Scholar 

  15. S. A. Ponomarenko, E. A. Rebrov, A. Yu. Bobrovsky, N. I. Boiko, A. M. Muzafarov, V. P. Shibaev, Liq. Cryst., 1996, 21, 1.

    Article  CAS  Google Scholar 

  16. K. Lorenz, H. Frey, B. Stuühn, R. Mülhaupt, Macromolecules, 1997, 30, 6860.

    Article  CAS  Google Scholar 

  17. S. A. Ponomarenko, N. I. Boiko, V. P. Shibaev, R. M. Richardson, I. J. Whitehouse, E. A. Rebrov, A. M. Muzafarov, Macromolecules, 2000, 33, 5549.

    Article  CAS  Google Scholar 

  18. M. Arseneault, I. Levesque, J.-F. Morin, Macromolecules, 2012, 45, 3687.

    Article  CAS  Google Scholar 

  19. E. R. Gillies, J. M. J. Frechet, J. Am. Chem. Soc., 2002, 124, 14137.

    Article  CAS  Google Scholar 

  20. C. C. Lee, J. A. MacKay, J. M. J. Frechet, F. C. Szoka, Nat. Biothechnol., 2005, 23, 1517.

    Article  CAS  Google Scholar 

  21. S. C. Han, J. H. Kim, J. W. Lee, Bull. Korean Chem. Soc., 2012, 33, 3501.

    Article  CAS  Google Scholar 

  22. A. S. Tereshchenko, E. V. Getmanova, A. I. Buzin, G. M. Ignat’eva, E. A. Tatarinova, A. V. Bystrova, V. D. Myakushev, A. M. Muzafarov, Russ. Chem. Bull. (Int. Ed.), 2007, 56, 2200 [Izv. Akad. Nauk, Ser. Khim., 2007, 2125].

    Article  CAS  Google Scholar 

  23. N. A. Sheremetyeva, N. V. Voronina, A. V. Bystrova, V. D. Miakushev, M. I. Buzin, A. M. Muzafarov, ACS Symp. Ser., 2010, 1051, 111.

    Article  CAS  Google Scholar 

  24. R. Gunawidjaja, Y. N. Luponosov, F. Huang, S. A. Ponomarenko, A. M. Muzafarov, V. V. Tsukruk, Langmuir, 2009, 25, 9270.

    Article  CAS  Google Scholar 

  25. N. A. Shumilkina, V. D. Myakushev, E. A. Tatarinova, M. I. Buzin, N. V. Voronina, T. V. Laptinskaya, O. M. Gallyamov, A. R. Khokhlov, A. M. Muzafarov, Polym. Sci., Ser. A (Engl. Transl.), 2006, 48, 1240 [Vysokomol. Soedin., Ser. A, 2006, 48, 2102].

    Article  Google Scholar 

  26. K. Lorenz, R. Mulhaupt, H. Frey, U. Rapp, F. J. Mayer-Posner, Macromolecules, 1995, 28, 6657.

    Article  CAS  Google Scholar 

  27. K. L. Wooley, C. J. Hawker, J. M. Pochan, G. M. J. Frechet, Macromolecules, 1993, 26, 1514.

    Article  CAS  Google Scholar 

  28. D. J. Crisp, in Surface Phenomena in Chemistry and Biology, Ed. J. F. Danielli, Pergamon, New York, 1958.

  29. D. J. Kuzmenka, S. Granick, Macromolecules, 1988, 21, 779.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. N. S. Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, 70 ul. Profsoyuznaya, 117393, Moscow, Russian Federation

    N. A. Novozhilova, Yu. N. Malakhova, A. I. Buzin, E. A. Tatarinova, N. G. Vasilenko & A. M. Muzafarov

  2. National Research Center “Kurchatov Institute,”, 1 pl. Akademika Kurchatova, 123182, Moscow, Russian Federation

    Yu. N. Malakhova

  3. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    M. I. Buzin & A. M. Muzafarov

Authors
  1. N. A. Novozhilova
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  2. Yu. N. Malakhova
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  3. M. I. Buzin
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  4. A. I. Buzin
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  5. E. A. Tatarinova
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  6. N. G. Vasilenko
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  7. A. M. Muzafarov
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Correspondence to A. M. Muzafarov.

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Dedicated to Academician of the Russian Academy of Sciences M. P. Egorov on the occasion of his 60th anniversary.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2514–2526, Novemer, 2013.

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Novozhilova, N.A., Malakhova, Y.N., Buzin, M.I. et al. Synthesis and properties of carbosilane dendrimers of the third and sixth generations with the ethylene oxide surface layer in bulk and in monolayers at the air-water interface. Russ Chem Bull 62, 2514–2526 (2013). https://doi.org/10.1007/s11172-013-0365-x

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  • DOI: https://doi.org/10.1007/s11172-013-0365-x

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