Abstract
The reaction of cis-dichlorobis(2,6-xylylisocyanide)palladium(ii) with 2-aminopyrazine affords a binuclear palladium complex, in which one of the metal atoms is involved in the palladacyclic ligand. In the contrast, the coupling of isocyanide ligands in cis-dichlorobis-(2,6-xylylisocyanide)palladium(ii) with another C-amino aza-substituted heterocycle, viz.,4-acetyl-3-amino-5-methylpyrazole, gives a mononuclear cationic palladium diaminocarbene complex. Both compounds were characterized by elemental analysis, IR spectroscopy, 1H, 13C{1H}, DEPT90/DEPT135, and 1H,13C-HSQC/1H,13C-HMBC NMR spectroscopy, high-resolution electrospray ionization mass spectrometry, and X-ray diffraction.
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Dedicated to Academician of the Russian Academy of Sciences I. P. Beletskaya on the occasion of her anniversary.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 0757–0765, March, 2013.
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Kinzhalov, M.A., Luzyanin, K.V., Boyarskiy, V.P. et al. Coupling of C-amino aza-substituted heterocycles with an isocyanide ligand in palladium(ii) complex. Russ Chem Bull 62, 758–766 (2013). https://doi.org/10.1007/s11172-013-0103-4
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DOI: https://doi.org/10.1007/s11172-013-0103-4