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Synthesis and structure of chiral coordination polymers of CoII, CuII, and MgII saccharates

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Abstract

Chiral metal-organic coordination polymers [Co2(sacch)2]·1/2H2O·CH3OH (1), [Cu(sacch)(H2O)2]·3H2O (2), and [Mg(H2O)3(sacch)] (3) (H2sacch is d-saccharic acid) were synthesized from aqueous or water-methanol solutions of potassium hydrogen saccharate and a salt of the corresponding metal. The compositions and structures of the resulting compounds were determined by single-crystal X-ray diffraction and confirmed by X-ray powder diffraction, IR spectroscopy, thermogravimetry, and elemental analysis.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrentieva, 630090, Novosibirsk, Russian Federation

    M. S. Zavakhina, D. G. Samsonenko, D. N. Dybtsev, M. P. Yutkin, A. V. Virovets & V. P. Fedin

  2. Novosibirsk State University, 2 ul. Pirogova, 630090, Novosibirsk, Russian Federation

    D. G. Samsonenko, D. N. Dybtsev & V. P. Fedin

Authors
  1. M. S. Zavakhina
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  2. D. G. Samsonenko
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  3. D. N. Dybtsev
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  4. M. P. Yutkin
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  5. A. V. Virovets
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  6. V. P. Fedin
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Corresponding author

Correspondence to V. P. Fedin.

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Dedicated to Academician of the Russian Academy of Sciences I. P. Beletskaya on the occasion of her anniversary.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 0716–0721, March, 2013.

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Zavakhina, M.S., Samsonenko, D.G., Dybtsev, D.N. et al. Synthesis and structure of chiral coordination polymers of CoII, CuII, and MgII saccharates. Russ Chem Bull 62, 716–721 (2013). https://doi.org/10.1007/s11172-013-0098-x

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  • DOI: https://doi.org/10.1007/s11172-013-0098-x

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