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Synthesis and aminomethylation of some heterocyclic α-nitroxyalkyl NH acids

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Abstract

The recently discovered synthetic route to quaternary ammonium salts of a new series via N-aminometylation of 4,4-bis(nitroxymethyl)oxazolidin-2-one was extended to other NH acids obtained for the first time by O-nitration of known a-hydroxyalkyl derivatives of 4-methyloxazolidin-2-one, pyrrolidin-2-one, and benzimidazole. In the aminomethylation of these NH acids, dimethylamine and morpholine were used as the amine components.

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Correspondence to A. G. Korepin.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2079–2084, November, 2012.

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Korepin, A.G., Romanova, L.B., Glushakova, N.M. et al. Synthesis and aminomethylation of some heterocyclic α-nitroxyalkyl NH acids. Russ Chem Bull 61, 2096–2101 (2012). https://doi.org/10.1007/s11172-012-0293-1

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  • DOI: https://doi.org/10.1007/s11172-012-0293-1

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