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Exchange and dative coordinate bonds in binuclear zinc complex

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Abstract

The high-resolution X-ray diffraction study of dizinc bis(pyridine)-bis{[μ2-(2-oxybenzylidene)amino]-4,6-di(tert-butyl)phenoxide} and the analysis of the structures of related compounds refuted the data on the effect of the exchange or dative mechanism of the metalbridging ligand bond formation on the bond strength and revealed the factors controlling the energy of these bonds.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    A. O. Borisova & K. A. Lyssenko

  2. Southern Scientific Center of Russian Academy of Sciences, 41 ul. Chekhova, 344006, Rostov-on-Don, Russian Federation

    D. A. Garnovskii

  3. Institute of Physical and Organic Chemistry, Southern Federal University, 194/2 prosp. Stachki, 344090, Rostov-on-Don, Russian Federation

    E. V. Korshunova, A. I. Uraev & A. S. Burlov

Authors
  1. A. O. Borisova
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  2. D. A. Garnovskii
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  3. E. V. Korshunova
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  4. A. I. Uraev
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  5. A. S. Burlov
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  6. K. A. Lyssenko
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Corresponding author

Correspondence to K. A. Lyssenko.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2053–2058, November, 2012.

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Borisova, A.O., Garnovskii, D.A., Korshunova, E.V. et al. Exchange and dative coordinate bonds in binuclear zinc complex. Russ Chem Bull 61, 2070–2075 (2012). https://doi.org/10.1007/s11172-012-0289-x

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  • DOI: https://doi.org/10.1007/s11172-012-0289-x

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