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Specific Features of the Molecular Structure of A New 3-(Benzo[d]Oxazole-2-Yl)- 1-(2-(1,3,3-Trimethylindoline-2-Ylidene) Ethylidene)Naphthalene-2(1H)-One Zinc Chloride Complex

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Abstract

X-ray diffraction is used to determine the structure of a new 3-(benzo[d]oxazole-2-yl)-1-(2-(1,3,3- trimethylindoline-2-ylidene)ethylidene)naphthalene-2(1H)-one zinc chloride complex 1. It is demonstrated that the ligand molecule in complex 1 has a trans–trans–cis conformation in which the indoline nitrogen atom is oriented in the same direction as the chelate ring, which could promote an additional coordination with the complexing atom.

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russia

    V. V. Tkachev & A. N. Utenyshev

  2. Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russia

    A. I. Chernyshov

  3. Peoples’ Friendship University of Russia, Moscow, Russia

    O. V. Kovalchukova

  4. Sechenov First Moscow State Medical University of the Ministry of Health of the Russian Federation, Moscow, Russia

    A. N. Utenyshev

Authors
  1. V. V. Tkachev
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  2. A. N. Utenyshev
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  3. A. I. Chernyshov
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  4. O. V. Kovalchukova
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Correspondence to V. V. Tkachev.

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Original Russian Text © 2018 V. V. Tkachev, A. N. Utenyshev, A. I. Chernyshov, O. V. Kovalchukova.

Translated from Zhurnal Strukturnoi Khimii, Vol. 59, No. 2, pp. 438–441, March–April, 2018.

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Tkachev, V.V., Utenyshev, A.N., Chernyshov, A.I. et al. Specific Features of the Molecular Structure of A New 3-(Benzo[d]Oxazole-2-Yl)- 1-(2-(1,3,3-Trimethylindoline-2-Ylidene) Ethylidene)Naphthalene-2(1H)-One Zinc Chloride Complex. J Struct Chem 59, 425–428 (2018). https://doi.org/10.1134/S0022476618020245

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  • DOI: https://doi.org/10.1134/S0022476618020245

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