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Interaction of the Negishi reagent Cp2ZrBun 2 with 1,4-bis(tert-butyl)butadiyne

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Abstract

The interaction of the Negishi reagent Cp2ZrBun 2 with 1,4-bis(tert-butyl)butadiyne ButC≡C-C≡CBut leads to four products: a five-membered zirconacyclocumulene complex Cp2Zr(η4-ButC4But) (2) synthesized earlier by another method, the previously unknown seven-membered zirconacyclocumulene Cp2Zr[η4-ButC4(But)-C(C2But)=CBut] (3) as well as small amounts of the zirconocene binuclear butatrienyl complex Cp2(Bun)Zr(ButC4But)Zr(Bun)Cp2 (4), and the dimeric acetylide [Cp2ZrC≡CBut]2 (5). The structure of complexes 2–5 was established by X-ray diffraction studies.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    V. V. Burlakov, V. S. Bogdanov, K. A. Lyssenko, P. V. Petrovskii, M. Kh. Minacheva, B. N. Strunin & V. B. Shur

  2. Leibniz Institute of Catalysis, Rostock University, 29a Albert Einstein Strasse, D-18059, Rostock, Germany

    A. Spannenberg, W. Baumann, P. Arndt & U. Rosenthal

Authors
  1. V. V. Burlakov
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  2. V. S. Bogdanov
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  3. K. A. Lyssenko
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  4. A. Spannenberg
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  5. P. V. Petrovskii
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  6. W. Baumann
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  7. P. Arndt
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  8. M. Kh. Minacheva
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  9. B. N. Strunin
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  10. U. Rosenthal
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  11. V. B. Shur
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Corresponding author

Correspondence to V. B. Shur.

Additional information

Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Strasse 29a, D-18059 Rostock, Germany.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 163–170, January, 2012.

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Burlakov, V.V., Bogdanov, V.S., Lyssenko, K.A. et al. Interaction of the Negishi reagent Cp2ZrBun 2 with 1,4-bis(tert-butyl)butadiyne. Russ Chem Bull 61, 165–173 (2012). https://doi.org/10.1007/s11172-012-0023-8

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  • DOI: https://doi.org/10.1007/s11172-012-0023-8

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