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Reactivity of 1,4-Diaza-1,3-Butadienes towards Cu(II) Pivalate: A Rare Case of Polymeric Structure Formed by Bridging Diazabutadiene Ligands

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Abstract

The reaction of copper(II) trimethylacetate, [Cu(Piv)2]n (Piv = (Me)3CCOO−), with 1,4-bis(R)-1,4-diaza-1,3-butadienes (R-DAD, R = 2,4,6-trimethylphenyl, Mes, or 2,6-diisopropylphenyl, dpp) in tetrahydrofuran afforded the coordination polymers [Cu2(Piv)4(Mes-DAD)]n (I) and [Cu2(Piv)4(dpp-DAD)]n (II). The structure of complexes in the crystal was determined by X-ray diffraction (CCDC nos. 2205866, 2205867). The products were shown to be 1D coordination polymers in which the binuclear {Cu2(Piv)4} moieties are linked into chains owing to the bridging function of 1,4-diaza-1,3-butadienes, which is unusual for this type of ligands.

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ACKNOWLEDGMENTS

This research was performed using the equipment of the JRC PMR IGIC RAS, supported by the state assignment of the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, in the field of fundamental research.

Funding

The work was supported by the Ministry of Science and Higher Education of Russia as part of the state assignment of Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    J. K. Voronina, A. S. Gavronova, D. S. Yambulatov, S. A. Nikolaevskii, M. A. Kiskin & I. L. Eremenko

  2. Higher Chemical College of the Russian Academy of Sciences, Mendeleev University of Chemical Technology of Russia, 125047, Moscow, Russia

    A. S. Gavronova

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  1. J. K. Voronina
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  2. A. S. Gavronova
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Correspondence to D. S. Yambulatov.

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Translated by Z. Svitanko

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Voronina, J.K., Gavronova, A.S., Yambulatov, D.S. et al. Reactivity of 1,4-Diaza-1,3-Butadienes towards Cu(II) Pivalate: A Rare Case of Polymeric Structure Formed by Bridging Diazabutadiene Ligands. Russ J Coord Chem 48, 916–923 (2022). https://doi.org/10.1134/S1070328422700154

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