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Synthesis and structures of the CH acid salts obtained in the reactions of malonic acid esters and malononitriles with 2,4,6-trinitrohalobenzenes in the presence of triethylamine

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Abstract

Reactions of dimethyl malonate, diphenyl malonate, methyl cyanoacetate, and malononitrile with 1-chloro-2,4,6-trinitrobenzene or 1-fluoro-2,4,6-trinitrobenzene in the presence of triethylamine in organic solvents gave stable brightly colored crystalline triethylammonium salts of the corresponding 2,4,6-trinitrophenylmalonic acid derivatives.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    Yu. G. Gololobov, S. V. Barabanov, A. S. Peregudov, P. V. Petrovskii, Z. A. Starikova, V. N. Khrustalev & I. A. Garbuzova

Authors
  1. Yu. G. Gololobov
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  2. S. V. Barabanov
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  3. A. S. Peregudov
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  4. P. V. Petrovskii
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  5. Z. A. Starikova
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  6. V. N. Khrustalev
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  7. I. A. Garbuzova
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Corresponding author

Correspondence to Yu. G. Gololobov.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1637–1645, August, 2011.

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Gololobov, Y.G., Barabanov, S.V., Peregudov, A.S. et al. Synthesis and structures of the CH acid salts obtained in the reactions of malonic acid esters and malononitriles with 2,4,6-trinitrohalobenzenes in the presence of triethylamine. Russ Chem Bull 60, 1663–1671 (2011). https://doi.org/10.1007/s11172-011-0249-x

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  • DOI: https://doi.org/10.1007/s11172-011-0249-x

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