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Electrochemical investigation of complexation of polymer ligands containing 2,2′-biquinolyl fragments with NiII ions in solution

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Abstract

Polyamic acids containing biquinolyl (biQ) fragments in the polymer backbone are capable of coordinating with NiII ions to form two types of coordination units: with one or two biQ ligands in the Ni coordination environment. The relative number of [Ni(biQ)2]2+ coordination units in the polymer chain increases with an increase in the concentration of the biQ fragments in solution and with a decrease in the conformational rigidity of the polymer. The synthesis of the nickel complexes with the polymer ligands can be carried out using both Ni salts and the electrochemical dissolution of the Ni anode.

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Authors and Affiliations

  1. Department of Chemistry, M. V. Lomonosov Moscow State University, 1/3 Leninskie Gory, 119991, Moscow, Russian Federation

    T. V. Magdesieva, O. M. Nikitin & S. M. Masoud

  2. Institute of Macromolecular Compounds, Russian Academy of Sciences, 31 Bol’shoi prosp. 31, 199004, St. Petersburg, Russian Federation

    A. V. Yakimansky, M. Ya. Goikhman & I. V. Podeshvo

Authors
  1. T. V. Magdesieva
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  2. O. M. Nikitin
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  3. S. M. Masoud
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  4. A. V. Yakimansky
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  5. M. Ya. Goikhman
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  6. I. V. Podeshvo
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Correspondence to T. V. Magdesieva.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1576–1582, August, 2011.

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Magdesieva, T.V., Nikitin, O.M., Masoud, S.M. et al. Electrochemical investigation of complexation of polymer ligands containing 2,2′-biquinolyl fragments with NiII ions in solution. Russ Chem Bull 60, 1601–1607 (2011). https://doi.org/10.1007/s11172-011-0239-z

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  • DOI: https://doi.org/10.1007/s11172-011-0239-z

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