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Carboranyl phosphites: the electronic effect in the Suzuki- Miyaura reaction

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Abstract

Isomeric carborane-containing phosphite ligands possessing different electronic properties have been synthesized. Their use in the Pd-catalyzed Suzuki-Miyaura reaction involving activated aryl bromides showed that phosphite with 9-o-carborane substituent has proved more efficient, with carboranyl phosphite having 1-m- carborane fragment being more efficient in the reactions with nonactivated aryl bromides.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    S. E. Lyubimov, T. A. Verbitskaya, E. G. Rys, P. V. Petrovskii, M. M. Ilín, V. A. Davankov & V. N. Kalinin

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  1. S. E. Lyubimov
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  2. T. A. Verbitskaya
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  3. E. G. Rys
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  4. P. V. Petrovskii
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  5. M. M. Ilín
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  6. V. A. Davankov
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  7. V. N. Kalinin
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Correspondence to V. N. Kalinin.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1620-1622, August, 2010.

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Lyubimov, S.E., Verbitskaya, T.A., Rys, E.G. et al. Carboranyl phosphites: the electronic effect in the Suzuki- Miyaura reaction. Russ Chem Bull 59, 1665–1667 (2010). https://doi.org/10.1007/s11172-010-0292-z

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  • DOI: https://doi.org/10.1007/s11172-010-0292-z

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